The p–n heterojunction could enhance the photocatalytic RhB degradation performance of Cu/g-C ₃ N ₄ .

An efficient palladium-catalyzed bisthiolation of terminal alkynes and arylhydrazines with Na₂S₂O₃ as the sulfur source for the assembly of (Z)-1,2-bis(arylthio)alkene derivatives is described.

Tetrahydrofuran scaffolds have found promising applications in both pharmaceutical chemistry and organic synthesis but remain underexplored owing to the challenges associated with their preparation. Herein, we have developed a robust synthetic strategy for the palladium-catalyzed cascade annulation reaction of buta-1,3-dienes with alkynols for the assembly of diverse 3-methylenetetrahydrofurans with excellent functional group compatibility and good regioselectivity. More importantly, this protocol features broad substrate scope, good functional group tolerance, and good step- and atom-economy. A diverse array of functional groups such as halogen atoms, aldehyde, nitro, ester, and several aromatic heterocycles were also nicely tolerated and provided the corresponding products in moderate to good yields. It is noteworthy that the practicability is further verified by gram-scale experiments and synthetic transformation to access organic functional molecules.