David Lee Phillips

Prof. Dr. David Lee Phillips

Department of Chemistry, The University of Hong Kong, Hong Kong, China
orcid

Research Focus & Metrics

Academic Career Length

36Years (1991-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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14 November 2019 in Nature Communications
Verified
Journal Article
Open access
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XZXuepeng Zhang
Xuepeng Zhang
Lili DULili DU
Lili DU
WZWeijun Zhao
Weijun Zhao
ZZZheng Zhao
Zheng Zhao
YXYu Xiong
Yu Xiong
Ben Zhong TangBen Zhong Tang
Ben Zhong Tang
Purely organic room temperature phosphorescence (RTP) has attracted wide attention recently due to its various application potentials. However, ultralong RTP (URTP) with high efficiency is still rarely achieved. Herein, by dissolving 1,8-naphthalic anhydride in certain organic solid hosts, URTP with a lifetime of over 600 ms and overall quantum yield of over 20% is realized. Meanwhile, the URTP can also be achieved by mechanical excitation when the host is mechanoluminescent. Femtosecond transient absorption studies reveal that intersystem crossing of the host is accelerated substantially in the presence of a trace amount of 1,8-naphthalic anhydride. Accordingly, we propose that a cluster exciton spanning the host and guest forms as a transient state before the guest acts as an energy trap for the RTP state. The cluster exciton model proposed here is expected to help expand the varieties of purely organic URTP materials based on an advanced understanding of guest/host combinations.

24 April 2018 in Chemical Science
Verified
Journal Article
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YCYuanjing Cai
Yuanjing Cai
Lili DULili DU
Lili DU
KSKerim Samedov
Kerim Samedov
XGXinggui Gu
Xinggui Gu
FQFei Qi
Fei Qi
Ben Zhong TangBen Zhong Tang
Ben Zhong Tang
Aggregation-induced emission (AIE) is the long-sought solution to the problem of aggregation-caused quenching that has hampered efficient application of fluorescent organic materials. An important goal on the way to fully understand the working mechanism of the AIE process was, for more than a decade, and still remains obtaining more comprehensive insights into the correlation between the ultrafast excited-state dynamics in tetraphenylethylene (TPE)-based molecules and the AIE effect in them. Here we report a number of TPE-based derivatives with varying structural rigidities and AIE properties. Using a combination of ultrafast time-resolved spectroscopy and computational studies, we observe a direct correlation between the state-dependent coupling motions and inhibited fluorescence, and prove the existence of photocyclized intermediates in them. We demonstrate that the dominant non-radiative relaxation dynamics, i.e. formation of intermediate or rotation around the elongated CC bond, is responsible for the AIE effect, which is strongly structure-dependent but not related to structural rigidity.

5 December 2022 in Energy & Environmental Science
Verified
Journal Article
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WWWenchao Wang
Wenchao Wang
LDLili Du
Lili Du
RXRuiqin Xia
Ruiqin Xia
RLRunhui Liang
Runhui Liang
TZTao Zhou
Tao Zhou
ZGZhengxiao Guo
Zhengxiao Guo
Efficient photocatalytic solar-to-H2conversion is pivotal to zero-carbon energy supply.


4 July 2019 in Nature Communications
Verified
Journal Article
Open access
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ZZZheng Zhao
Zheng Zhao
XZXiaoyan Zheng
Xiaoyan Zheng
Lili DULili DU
Lili DU
YXYu Xiong
Yu Xiong
WHWei He
Wei He
Ben Zhong TangBen Zhong Tang
Ben Zhong Tang
Aggregation-induced emission (AIE) is a photophysical phenomenon correlated closely with the excited-state intramolecular motions. Although AIE has attracted increasing attention due to the significant applications in biomedical and optoelectronics, an in-depth understanding of the excited-state intramolecular motion has yet to be fully developed. Here we found the non-aromatic annulene derivative of cyclooctatetrathiophene shows typical AIE phenomenon in spite of its rotor-free structure. The underlying mechanism is investigated through photoluminescence spectra, time-resolved absorption spectra, theoretical calculations, circular dichroism as well as by pressure-dependent fluorescent spectra etc., which indicate that the aromaticity reversal from ground state to the excited state serves as a driving force for inducing the excited-state intramolecular vibration, leading to the AIE phenomenon. Therefore, aromaticity reversal is demonstrated as a reliable strategy to develop vibrational AIE systems. This work also provides a new viewpoint to understand the excited-state intramolecular motion behavior of lumiongens.

20 January 2022 in Journal of the American Chemical Society
Verified
Journal Article
Closed access
PAParvej Alam
Parvej Alam
TCTsz Shing Cheung
Tsz Shing Cheung
NLNelson L. C. Leung
Nelson L. C. Leung
JZJianyu Zhang
Jianyu Zhang
JGJing Guo
Jing Guo
Ben Zhong TangBen Zhong Tang
Ben Zhong Tang