The carbon (C) and nitrogen (N) ratio is a key indicator of nutrient utilization and limitations in rangelands. To understand the distribution of herbivores and grazing patterns, information on grass quality and quantity is important. In heterogeneous environments, remote sensing offers a timely, economical, and effective method for assessing foliar biochemical ratios at varying spatial and temporal scales. Hence, this study provides a synopsis of the advancement in remote sensing technology, limitations, and emerging opportunities in mapping the C:N ratio in rangelands. Specifically, the paper focuses on multispectral and hyperspectral sensors and investigates their properties, absorption features, empirical and physical methods, and algorithms in predicting the C:N ratio in grasslands. Literature shows that the determination of the C:N ratio in grasslands is not in line with developments in remote sensing technologies. Thus, the use of advanced and freely available sensors with improved spectral and spatial properties such as Sentinel 2 and Landsat 8/9 with sophisticated algorithms may provide new opportunities to estimate C:N ratio in grasslands at regional scales, especially in developing countries. Spectral bands in the near-infrared, shortwave infrared, red, and red edge were identified to predict the C:N ratio in plants. New indices developed from recent multispectral satellite imagery, for example, Sentinel 2 aided by cutting-edge algorithms, can improve the estimation of foliar biochemical ratios. Therefore, this study recommends that future research should adopt new satellite technologies with recent development in machine learning algorithms for improved mapping of the C:N ratio in grasslands.

Unfettered agricultural activities have severely degraded vast areas of grasslands over the last decade. To rehabilitate and restore the productivity in affected grasslands, rangeland management practices still institute vast nitrogen-based fertilization regimes. However, excessive fertilization can often have damaging environmental effects. Over-fertilization can lead to nitrogen saturation. Although early indicators of nitrogen saturation have been documented, research detailing the near-real-time nitrogen saturation status of grasslands is required to better facilitate management protocols and optimize biomass production within degraded grasslands. Hence, the aim of this study was to discriminate nitrogen-saturated tropical grasses grown under a diverse fertilization treatment trial, using Worldview-3 satellite imagery and decision tree techniques. To accomplish this, nitrogen-saturated plots were first identified through specific physiological-based criteria. Thereafter, Worldview-3 satellite imagery (400–1040 nm) and decision tree techniques were applied to discriminate between nitrogen-saturated and -unsaturated grassland plots. The results showed net nitrate (NO₃⁻-N) concentrations and net pH levels to be significantly different (α = 0.05) between saturated and non-saturated plots. Moreover, the random forest model (overall accuracy of 91%) demonstrated a greater ability to classify saturated plots as opposed to the classification and regression tree method (overall accuracy of 79%). The most important variables for classifying saturated plots were identified as: the Red-Edge (705–745 nm), Coastal (400–450 nm), Near-Infrared 3 (838–950 nm), Soil-Adjusted Vegetation Index (SAVI) and the Normalized Difference Vegetation Index 3 (NDVI3). These results provide a framework to assist rangeland managers in identifying grasslands within the initial stages of nitrogen saturation. This will enable fertilization treatments to be adjusted in near-real-time according to ecosystem demand and thereby maintain the health and longevity of Southern African grasslands.