Amidst the dual global pressures of plastic pollution and resource scarcity, the transition to a circular economy has become an imperative. The valorization of biomass waste from agricultural, food, and animal processing into biodegradable packaging materials presents a key strategy to address this challenge. This review aims to systematically construct a comprehensive knowledge framework for the field, addressing the thematic fragmentation and methodological limitations of existing literature through integrated cross-stream analysis, combined bibliometric and technological assessment, and identification of emerging research frontiers. We begin with a bibliometric analysis to delineate the field’s evolutionary trajectory since 2008, global collaboration networks, core research themes, and emerging frontiers, revealing a clear progression from environmental impact assessment to functional material innovation. Subsequently, this review delves into the complete technological chain, from the green extraction of bio-based materials from three major waste streams to the comparison of traditional and advanced film fabrication methods. We then elaborate on the critical performance evaluation dimensions, including mechanical, barrier, biodegradable, safety, and functional properties, and summarize current applications in sectors such as food and medicine. Finally, we critically assess the core challenges related to cost, performance stability, and large-scale production, and provide a systematic outlook on future research directions, particularly the development of high-performance, multifunctional, and intelligent materials. This review offers a comprehensive and data-driven reference framework for researchers and industry stakeholders in the field.

Two-photon microscopy (TPM) has become an indispensable tool in the life sciences, offering exceptional spatial resolution, deep tissue penetration, and low phototoxicity. It provides a revolutionary solution for long-term dynamic observation of living cells and tissues. This article systematically explains the working principles of TPM and reviews its applications in cutting-edge fields such as neuroscience, immunology, oncology, regenerative science and plant biology, highlighting its remarkable multidisciplinary adaptability. Building on this foundation, we further explore the breakthrough directions and future prospects for the development of this technology.

The increasing use of cerium oxide nanoparticles (CeO₂-NPs) has raised concerns regarding their environmental fate and biological effects in soil–plant systems. This review uses cerium oxide nanoparticles (CeO₂-NPs) as a mechanistically well-characterized case study to examine relationships among dose, chemical speciation, and plant responses, with emphasis on Ce³⁺/Ce⁴⁺ redox cycling and condition-dependent, nanozyme-like activity. We discuss how particle size, surface charge, Ce³⁺/Ce⁴⁺ ratio, and coating interact with rhizosphere processes, including organic acid complexation, phosphate-mediated CePO₄ immobilization, and potentially microbially mediated transformation, to influence effective root-surface exposure. The resulting particulate, ionic, and secondary transformation-product pools affect root uptake, vascular transport, redox homeostasis, metabolism, and hormone-associated signaling. Major limitations include weak causal links between rhizosphere speciation and bioavailability, insufficient separation of particulate and ionic contributions, limited integration of multi-omics with speciation data, and uncertain extrapolation from hydroponic to soil systems. Standardized exposure protocols, integrated XANES, spICP-MS, and imaging workflows, and long-term soil studies are therefore required. Other rare-earth nanomaterials are discussed only briefly to define the material-specific boundaries of the CeO₂-centered framework.

The flooded rice rhizosphere is a continuous reactive interface composed of sediment, porewater, root-surface oxic microdomains, and iron plaque, where redox processes and Fe cycling regulate Cd/As speciation, bioavailability, and plant accumulation. Engineered nanomaterials (ENMs) have shown potential for reducing Cd/As uptake in rice, but the coupled roles of microbial community responses, iron-plaque gating, and cross-interface elemental migration remain insufficiently integrated. This review synthesizes the current evidence on ENM transformation and partitioning at flooded rhizosphere microinterfaces, focusing on front-end speciation changes, root-surface retention, microbial functional regulation, and plant sequestration or transport. Correlative evidence suggests that rhizosphere microorganisms are associated with altered redox conditions, Fe cycling, As methylation potential, and metabolite secretion, which may influence Cd/As partitioning and cross-interface migration. However, direct causal validation of the complete ENM transformation–microbial response–Fe cycling–Cd/As flux–grain accumulation sequence within a single integrated system remains lacking. We further discuss how elevated CO₂, micro-/nanoplastics, Fe/DOM dynamics, and water management regimes may modify this framework, and we identify Sb as a theoretical boundary case because direct ENM–rice evidence remains limited. Finally, we highlight the need to integrate spatial tracing and imaging methods, including persistent luminescence tracing, LA-ICP-MS, NanoSIMS, and µ-XRF/µ-XANES, with metaomics to connect particle localization, microbial function, and contaminant fate.

Aronia melanocarpa contains abundant phenolic compounds, including procyanidins, flavonols, flavan-3-ols, and phenolic acids, but its pronounced astringency limits its broader use in food applications. Catechol and other oxygen-donor motifs in plant phenolics are known to associate with Fe³⁺ and can support metal–phenolic assembly. In this study, ultrasound-assisted cellulase–pectinase extraction was used to recover an A. melanocarpa polyphenol extract, which was subsequently combined with Fe³⁺ to construct a plant-derived hair dye coating on keratin fibers. Under optimized extraction conditions, the total phenolic yield reached 82.315 mg gallic acid equivalents (GAE)/g dry fruit. A limited targeted LC–MS/MS panel was used to evaluate 12 selected non-anthocyanin phenolic analytes, including procyanidin dimers, a flavan-3-ol, flavonols, and phenolic acids; the contribution of the pH-sensitive anthocyanin fraction was not resolved. Among the tested metal ions, Fe³⁺ produced the strongest chromogenic response. The optimized L-cysteine pretreatment–Fe³⁺ mordanting–polyphenol dyeing sequence produced a ΔE* of 55.42. Adsorption experiments empirically described the uptake behavior of the polyphenol extract, whereas complementary surface, spectroscopic, elemental, diffraction, thermal, and wettability analyses were consistent with the presence of a relatively uniform Fe-containing polyphenol coating at the hair fiber interface. Neither the adsorption-model fits nor the individual characterization techniques uniquely resolved the underlying molecular mechanism. Preliminary HET-CAM, single-exposure dermal, and acute eye irritation assessments showed no obvious acute irritation under the tested conditions. An exploratory image-based analysis examined whether standardized hair tress photographs could approximate a predefined colorimetric score. Because only 30 independent original samples were available and no external validation was performed, this analysis was treated solely as a proof of concept. This laboratory proof-of-concept extends established Fe³⁺–polyphenol assembly chemistry to a compositionally complex A. melanocarpa extract for hair fiber coloration. Further work is required to clarify anthocyanin behavior, simplify the sequential protocol, and benchmark its performance against representative commercial hair dyes.