The internal moisture dynamics of an aged (> 100 years old) railway earthwork embankment, which is still in use, are investigated using 2D and 3D resistivity monitoring. A methodology was employed that included automated 3D ERT data capture and telemetric transfer with on‐site power generation, the correction of resistivity models for seasonal temperature changes and the translation of subsurface resistivity distributions into moisture content based on petrophysical relationships developed for the embankment material. Visualization of the data as 2D sections, 3D tomo‐grams and time series plots for different zones of the embankment enabled the development of seasonal wetting fronts within the embankment to be monitored at a high‐spatial resolution and the respective distributions of moisture in the flanks, crest and toes of the embankment to be assessed. Although the embankment considered here is at no immediate risk of failure, the approach developed for this study is equally applicable to other more high‐risk earthworks and natural slopes.
17 July 2007 in Journal of Environmental Science and Health, Part A
This paper presents a multi-laboratory comparison study of in vitro models assessing bioaccessibility of soil-bound lead in the human gastrointestinal tract under simulated fasted and fed conditions. Oral bioavailability data from a previous human in vivo study on the same soil served as a reference point. In general, the bioaccessible lead fraction was significantly (P < 0.05) different between the in vitro methods and ranged for the fasted models from 2% to 33% and for the fed models from 7% to 29%. The in vivo bioavailability data from literature were 26.2 ± 8.1% for fasted conditions, compared to 2.5 ± 1.7% for fed conditions. Under fed conditions, all models returned higher bioaccessibility values than the in vivo bioavailability; whereas three models returned a lower bioaccessibility than bioavailability under fasted conditions. These differences are often due to the method's digestion parameters that need further optimization. An important outcome of this study was the determination that the method for separating the bioaccessible lead from the non-bioaccessible fraction (centrifugation, filtration, ultrafiltration) is crucial for the interpretation of the results. Bioaccessibility values from models that use more stringent separation methods better approximate in vivo bioavailability results, yet at the expense of the level of conservancy. We conclude from this study that more optimization of in vitro digestion models is needed for use in risk assessment. Moreover, attention should be paid to the laboratory separation method since it largely influences what fraction of the contaminant is considered bioaccessible.