Large quantities of mineral dust particles are frequently ejected into the atmosphere through the action of wind. The surface of dust particles acts as a sink for many gases, such as sulfur dioxide. It is well known that under most conditions, sulfur dioxide reacts on dust particle surfaces, leading to the production of sulfate ions. In this report, for specific atmospheric conditions, we provide evidence for an alternate pathway in which a series of reactions under solar UV light produces first gaseous sulfuric acid as an intermediate product before surface-bound sulfate. Metal oxides present in mineral dust act as atmospheric photocatalysts promoting the formation of gaseous OH radicals, which initiate the conversion of SO₂to H₂SO₄in the vicinity of dust particles. Under low dust conditions, this process may lead to nucleation events in the atmosphere. The laboratory findings are supported by recent field observations near Beijing, China, and Lyon, France.

We have built an atom interferometer and, by applying an electric field on one of the two interfering beams, we have measured the static electric polarizability of lithium $\alpha =(24.33\pm 0.16)\times {10}^{-30}{\mathrm{m}}^3$ with a 0.66% uncertainty. Our experiment is similar to an experiment done on sodium in 1995 by Pritchard and co-workers, with several improvements: the electric field can be calculated analytically and the interference signals have a large intensity and a high visibility, resulting in accurate phase measurements. This experiment illustrates the extreme sensitivity of atom interferometry: when the atom enters the electric field, its velocity increases and the fractional change, equal to $4\times {10}^{-9}$ for our largest field, is measured with a ${10}^{-3}$ accuracy.

Diffraction of atoms by lasers is a very important tool for matter wave optics. Although the process is well understood, the phase shifts induced by this diffraction process are not well known. In this paper, we make analytical calculations of these phase shifts in some simple cases and use these results to model the contrast interferometer recently built by Pritchard and co-workers. We thus show that the values of the diffraction phases are large and that they probably contribute to the phase noise observed in this experiment.

During transport by advection, atmospheric nonspherical particles, such as volcanic ash, desert dust or sea-salt particles experience several chemical and physical processes, leading to a complex vertical atmospheric layering at remote sites where intrusion episodes occur. In this paper, a new methodology is proposed to analyse this complex vertical layering in the case of a two/three-component particle external mixtures. This methodology relies on an analysis of the spectral and polarization properties of the light backscattered by atmospheric particles. It is based on combining a sensitive and accurate UV-VIS polarization lidar experiment with T-matrix numerical simulations and air mass back trajectories. The Lyon UV-VIS polarization lidar is used to efficiently partition the particle mixture into its nonspherical components, while the T-matrix method is used for simulating the backscattering and depolarization properties of nonspherical volcanic ash, desert dust and sea-salt particles. It is shown that the particle mixtures' depolarization ratio δ _p differs from the nonspherical particles' depolarization ratio δ_ns due to the presence of spherical particles in the mixture. Hence, after identifying a tracer for nonspherical particles, particle backscattering coefficients specific to each nonspherical component can be retrieved in a two-component external mixture. For three-component mixtures, the spectral properties of light must in addition be exploited by using a dual-wavelength polarization lidar. Hence, for the first time, in a three-component external mixture, the nonsphericity of each particle is taken into account in a so-called 2β + 2δ formalism. Applications of this new methodology are then demonstrated in two case studies carried out in Lyon, France, related to the mixing of Eyjafjallajökull volcanic ash with sulfate particles (case of a two-component mixture) and to the mixing of dust with sea-salt and water-soluble particles (case of a three-component mixture). This new methodology, which is able to provide separate vertical profiles of backscattering coefficient for mixed atmospheric dust, sea-salt and water-soluble particles, may be useful for accurate radiative forcing assessments.