To protect carbon steel from degradation via corrosion, it is usually coated using a multilayer system of paints composed of petroleum-based polymers. The chemical industry is currently moving towards more sustainable chemistry, in which one of the main objectives is to reduce fossil fuel use and the derived raw materials. However, the replacement of petroleum-based raw materials with those that are bio-based is not straightforward since the properties of these new materials are often inferior to the traditional ones. One of the most used resins in primer paints is Diglycidyl ether bisphenol A (DGEBA). This is an epoxy resin synthesized from bisphenol A (BPA), a toxic and carcinogenic petroleum-based compound. This study investigates the substitution of the primer coating in a three-layer coating system with two different types of primer coating formulations, one which is partially bio-based and another that is BPA-free. The corrosion protection effectiveness of these sustainable coatings is assessed not only at the laboratory scale but also in real offshore conditions. Moreover, the adhesion of the different coating systems is evaluated before and after each ageing test. The results reveal that these novel coatings exhibit comparable performance to conventional paints while providing a more sustainable corrosion protection alternative.

Offshore corrosion is a critical issue for metallic offshore structures. In this study, we investigated the corrosion protection of 12 coating systems for offshore monopiles in atmospheric, splash, and submerged zones, and we compared their performance under accelerated laboratory testing according to ISO 12944 with real field exposure. The results showed that the aging of the coatings did not accelerate at the same rate in all coatings. Furthermore, we observed that for some types of laboratory tests, the results are not representative of real field exposure as the laboratory test is much less aggressive than the real offshore conditions. This observation confirms that the field exposure data provide valuable information in order to properly assess the corrosion protection of coatings and thus the expected lifetime of the offshore structure. Additionally, we analyzed the rate-determining steps involved in the application of the coating onto the entire monopile and quantified the possibility of achieving a more time efficient coating process. Our results contribute to a better understanding of the issues related to testing and qualification of corrosion protection coatings for offshore structures and provide useful insights for the selection of coating solutions at the industrial level.

This work aimed to develop new S355-based structural steels with enhanced marine corrosion resistance while preserving mechanical properties. Two alloying strategies (Cu/Ni and Al/Cr) were investigated. Conventional and new steel samples were produced and characterized for microstructure, mechanical properties, and corrosion. The new steels showed similar or improved mechanical properties. Potentiodynamic polarization tests indicated stabilization of the oxidation process in the new steels. Laboratory accelerated corrosion tests on painted specimens revealed reduced blistering at paint film defects for some new steels compared to conventional steel. Ongoing research includes evaluating painted specimens in a real offshore environment using an advanced floating laboratory