A possible way to store both renewable energy and CO ₂ in chemical energy is to produce value-added chemicals and fuels starting from CO ₂ and green electricity. This can be done by exploiting the non-equilibrium properties of gaseous electrical discharges. Discharges, in addition, can be switched on and off quickly, thus being suitable to be coupled with an intermittent energy source. In this study, we have used a nanosecond pulsed discharge to dissociate CO ₂ and CH ₄ in a 1:1 mixture at atmospheric pressure, and compared our results with literature data obtained by other discharges. The main products are CO, H ₂ , C ₂ H ₂ , water and solid carbon. We estimate an energy efficiency of 40% for syngas (CO and H ₂ ) production, higher if other products are also considered. Such values are among the highest compared to other discharges, and, although not very high on an absolute scale, are likely improvable via possible routes discussed in the paper and by coupling to the discharge a heterogeneous catalysis stage.