The rapid development of society and industry as well as the frequent occurrence of oil spills cause the shortage of fresh water resources, which not only affects human safety and life, but also impedes the world-wide sustainable development. To address these challenges, novel membrane materials with unique wettability properties have gained significant attention, particularly in the field of oil/water separation. In this research, we modified the hydrophobic PET fabric to achieve superhydrophilic characteristics using impregnation method. Subsequently, we electrospun hydrophobic PVDF fibers onto the superhydrophilic fabric surface, and PVDF/Ca₁₀(PO₄)₆(OH)₂@PET Janus membrane with asymmetric wettability was obtained. The membrane has an excellent unidirectional liquid transport capacity, and can effectively separate heavy oil or light oil, the separation efficiency is more than 90 %. The results also show that the Janus membrane can be used under alkaline conditions and has satisfactory tensile resistance and re-use performance. This work provides a new idea for Janus membrane design and effectively improves the application potential of the Janus membrane in the field of oil/water separation.

Fresh water scarcity has become a crisis affecting human survival and development. Atmospheric water capture with remarkable advantages such as energy-independence and low-cost is supposed to be a promising way to address the problem. Herein, a facile strategy is presented to design a membrane material with efficient atmospheric water capture capacity and high practical significancy. A hybrid Janus membrane with anisotropic wettability and morphology is fabricated by integrating electrospinning and in situ surface oxidation methods. Taking advantage of the anisotropic wettability and strong force provided by directional wicking to draw water drops from a hydrophobic to a hydrophilic layer, the Janus membrane exhibits novel directional water droplet transport and possesses efficient and excellent atmospheric water capture capacity. Janus membrane with larger pores in the hydrophobic layer shows higher atmospheric water capture capacity than that with smaller pores. Furthermore, the hybrid Janus membrane is successfully implemented in soil water retention in the plant cultivation process. This work provides an insight into the facile design of the Janus membrane for fresh water capture, which is important to extend its practical applications.

The PLA-E/TiO₂@PDA–PLA Janus membrane with asymmetric wettability exhibits efficient directional moisture transport and excellent UV protective capacity.

Novel hydrophobic/hydrophilic Janus fibrous membranes, the poly[4,4′-methylenebis (phenylisocyanate)-alt-1,4-butanediol/di(propylene glycol)/plycaprolactone] (PU) fibrous membrane as the hydrophobic layer and cellulose acetate (CA) fibrous membrane as the hydrophilic layer, were fabricated by the so-called “layer-by-layer” electrospinning technology. A series of the PU/CA Janus membranes with different electrospinning time of the CA layers by which the thickness of hydrophilic layer can be controlled were also prepared to uncover its influence on the directional water vapor transmission. The results showed that water vapor transmission capability from the hydrophobic side to the hydrophilic side of the PU/CA Janus fibrous membrane was enhanced rather than that from the reverse direction of the same membrane. The optimal water vapor transmission capacity existed when the electrospinning time of CA fibrous membrane reached 15 min. Such enhanced water vapor transmission originated because of the asymmetric wettability of the Janus membrane and the strong force to draw tiny water droplet from the hydrophobic side to the hydrophilic side. The novel understanding is useful for facile designing and fabrication of efficient moisture permeable fabrics and clothing.