The development of a second-order integral model for a round turbulent buoyant jet is reported based on new experimental data on turbulent mass and momentum transport. The mean and turbulent characteristics of a round vertical buoyant jet covering the full range from jets to plumes were investigated using a recently developed combined digital particle image velocimetry (DPIV) and planar laser-induced fluorescence (PLIF) system. The system couples the two well-known techniques to enable synchronized planar measurements of flow velocities and concentrations in a study area. The experimental results conserved the mass and momentum fluxes introduced at the source accurately with closure errors of less than 5%. The momentum flux contributed by turbulence and streamwise pressure gradient was determined to be about 10% of the local mean momentum flux in both jets and plumes. The turbulent mass flux, on the other hand, was measured to be about 7.6% and 15% of the mean mass flux for jets and plumes respectively. While the velocity spread rate was shown to be independent of the flow regime, the concentration-to-velocity width ratio λ varied from 1.23 to 1.04 during the transition from jet to plume. Based on the experimental results, a refined second-order integral model for buoyant jets that achieves the conservation of total mass and momentum fluxes is proposed. The model employs the widely used entrainment assumption with the entrainment coefficient taken to be a function of the local Richardson number. Improved prediction is achieved by taking into account the variation of turbulent mass and momentum fluxes. The variation of turbulent mass flux is modelled as a function of the local Richardson number. The turbulent momentum flux, on the other hand, is treated as a fixed percentage of the local mean momentum flux. In addition, unlike most existing integral models that assume a constant concentration-to-velocity width ratio, the present model adopts a more accurate approach with the ratio expressed as a function of the local Richardson number. As a result, smooth transition of all relevant mean and turbulent characteristics from jet to plume is predicted, which is in line with the underlying physical processes.

Porous copper sulfide–carbon composites with Cu _1.96 S uniformly dispersed within the well-graphitized carbon octahedra framework have been rationally fabricated by a green one-step MOFs-templated method.