Marcos Klunk

Dr. Marcos Klunk

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1 July 2020 in Energy
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Journal Article
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PWPaulo R. Wander
Paulo R. Wander
FBFlávio M. Bianchi
Flávio M. Bianchi
NCNattan R. Caetano
Nattan R. Caetano
MKMarcos Klunk
Marcos Klunk
MIMaria Luiza S. Indrusiak
Maria Luiza S. Indrusiak

13 February 2020 in Chemical Papers
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MKMarcos Klunk
Marcos Klunk
SSSuellen Brasil Schröpfer
Suellen Brasil Schröpfer
SDSudipta Dasgupta
Sudipta Dasgupta
MDMohuli Das
Mohuli Das
NCNattan Roberto Caetano
Nattan Roberto Caetano
CMCarlos Alberto Mendes Moraes
Carlos Alberto Mendes Moraes

1 October 2019 in ECS Journal of Solid State Science and Technology
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MKMarcos Klunk
Marcos Klunk
SDSudipta Dasgupta
Sudipta Dasgupta
MDMohuli Das
Mohuli Das
MCMarcelo Gregory Cunha
Marcelo Gregory Cunha
PWPaulo Roberto Wander
Paulo Roberto Wander
Application of efficient technologies is imperative to minimize the impact of textile effluents on the environment. A solution to this problem is the application of molecular sieves such as zeolites. The sodalite zeolite has structural characteristics that allow its application as an adsorbent of heavy metals and chromophoric groups, responsible for coloring the clothing fabric. The objective of this work was to synthesize and evaluate the application of sodalite zeolite with four Si/Al ratios (1.0, 1.5, 2.0 and 2.5), using organic template. X-ray diffraction exhibits the crystalline phases of sodalite zeolite, marking the presence of minerals like kaolinite, mullite and quartz. Cation-exchange-capacity is 37% more in case of 2.5-SOD zeolite, compared to that of 1.0-SOD in the zeolitization process. The dye adsorption process was efficient at low concentrations (5, 10 and 25 mg/L) of the textile dye than higher concentrations (50, 75 and 100 mg/L) of the dye and hence, determining the concentration of the dye was of fundamental importance for efficiency regarding color removal. Therefore, it can be concluded that the synthesized sodalite zeolites (with low concentrations) in our study have substantial success potential in the effective removal of dyes from the textile industry.

29 July 2020 in Inventions
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ZSZeban Shah
Zeban Shah
RVRenato Cataluña Veses
Renato Cataluña Veses
JBJonatan Brum
Jonatan Brum
MKMarcos Klunk
Marcos Klunk
LRLuiz Alberto Oliveira Rocha
Luiz Alberto Oliveira Rocha
NCNattan Caetano
Nattan Caetano
This work presents the production of sewage sludge oil by pyrolysis, shows the physicochemical properties and compares it with commercial diesel. The sewage sludge was dried and mixed to discarded cooking oil to increase the fuel conversion rate due to the pyrolysis process at an initial temperature of 25 °C and a final of 650 °C. The oil was distilled and analyzed in a Proton nuclear magnetic resonance (1H-NMR), Gas Chromatogram and Mass spectrometry (GC-MS), thermogravimetric analysis (TGA) and Fourier transform infrared spectroscopy (FTIR) to perform a structural characterization on the molecular distribution, groups of functions and the product thermal stability. The authors measured fundamental physicochemical properties like viscosity, density and flashpoint and compared the results with the corresponding commercial S-10 diesel properties observing good agreement.

24 October 2019 in International Journal of Environmental Studies
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Journal Article
Closed access
MKMarcos Klunk
Marcos Klunk
ZSZeban Shah
Zeban Shah
NCNattan Caetano
Nattan Caetano
RCRommulo Vieira Conceição
Rommulo Vieira Conceição
PWPaulo Roberto Wander
Paulo Roberto Wander
MDMohuli Das
Mohuli Das
Several Carbon Capture and Storage (CCS) techniques have been studied including injections of carbon dioxide (CO2) into the mature and/or depleted hydrocarbon reservoirs and deep saline aquifers. This work aims to test storing CO2 into the magnesium-rich evaporite strata and also into the stratigraphic intervals containing Mg-rich brines. The test simulates Mg-carbonation of the synthetic solution obtained from the Mg-evaporite mineral, bischofite – both experimentally in the laboratory condition and also through computerised geochemical simulation. The laboratory experiments, which resulted in the crystallisation of anhydrous magnesite, were analysed. The TOUGHREACTTM, Geochemist’s WorkbenchTM (GWB) and PHREEQCTM software simulated the experiments as computerised geochemical model and tested the results for natural geological conditions. The geochemical simulations successfully demonstrate the immense CCS potential for the Mg-evaporite (as well as the sedimentary strata charged with Mg-evaporitic brine) at their subsurface geological occurrences at elevated pressure-temperature and high salinity.

1 January 2020 in Materials Research Express
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Journal Article
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MKMarcos Klunk
Marcos Klunk
MDMohuli Das
Mohuli Das
SDSudipta Dasgupta
Sudipta Dasgupta
AIandrea impiombato
andrea impiombato
NCNattan Roberto Caetano
Nattan Roberto Caetano
CMCarlos Alberto Mendes Moraes
Carlos Alberto Mendes Moraes
Rice husk is considered as a waste in the rice industry but is proficient in manufacturing different materials, such as zeolites, which is produced in large quantities all over the world, for example in Brazil. Zeolite is an adsorbent support material, which can be synthesized from rice husk ash (RHA) with external sources of aluminium (ESA). The scientific community has been conducting several measures to minimize the environmental impacts caused by greenhouse gases. Several mitigation processes are presently investigated, which includes carbon dioxide injections into adsorbent materials (e.g. zeolites). The efficiency of this technology involves a zeolitic material with high crystallinity and high concentrations of SiO2 and Al2O3 (aluminosilicates). In the present work, zeolites have been synthesized from rice husk ash (SiO2 source) and external aluminium sources (Al2O3 - alumina, gibbsite and metakaolin) to fulfill that purpose. With the aid of XRF, XRD, SEM/EDS and FTIR techniques, the zeolitic material was characterized in two distinct crystalline phases: Mordenite and ZSM-5. The synthesis was carried out by the ideal addition of ESA (2.5 g) to RHA. According to the literature, the zeolitic materials formed by the mixture of Mordenite and ZSM-5 can be availed for gas separation and greenhouse gas storage.