Understanding the interaction of surface water and groundwater affected by anthropogenic activities is of great importance for water resource and water quality management. The Xiong’an New Area, located in the North China Plain, has been designated a new building area by China’s government. Groundwater has been over pumped and artificial water was transferred to meet the water supply in this region. Therefore, the natural interaction of surface water and groundwater has been greatly changed and there has been a complex impact of the groundwater from anthropogenic activities. In this study, we used water chemical ions and stable isotopes of δ²H and δ¹⁸O to assess the interaction of surface water and groundwater in the Xiong’an New Area. We carried out field surveys and water sampling of the Fu River (domestic waste water discharge), Lake Baiyangdian (artificial water transfer), and the underlying groundwater along the water bodies. Results show that the artificial surface water (discharged and transferred) became the major recharge source for the local groundwater due to the decline of groundwater table. We used groundwater table observations, end-member mixing analysis of the stable isotopic composition and chloride tracers to estimate the contributions of different recharge sources to the local groundwater. Due to the over pumping of groundwater, the lateral groundwater recharge was dominant with a contribution ratio ranging from 12% to 78% in the upper reach of the river (Sections 1–3). However, the contribution of lateral groundwater recharge was estimated to be negligible with respect to the artificial water recharge from Lake Baiyangdian. Seepage from the Fu River contributed a significant amount of water to the connecting aquifer, with a contribution ranging from 14% to 75% along the river. The extent of the river influence into the aquifer ranges as far as 1400 m to the south and 400 m to the north of the Fu River. Estimations based on isotopic fractionation shows that about 22.3% of Lake Baiyangdian water was lost by evaporation. By using the stable isotopes of oxygen and hydrogen in the lake water, an influencing range of 16 km west of the lake was determined. The interaction of the surface water and groundwater is completely changed by anthropogenic activities, such as groundwater over pumping, waste water discharge and water transfer. The switched interaction of surface water and groundwater has a significant implication on water resources management.

Nitrate contamination is a common problem in groundwater of the North China Plain (NCP) owing to overuse of fertilizers and discharge of wastewater. Accordingly, it is important to investigate nitrate contamination in recharge areas to understand the fate of nitrate in the plains area. In this study, the spatial and temporal distribution characteristics of nitrate and factors contributing to its sources and transformation in shallow groundwater of the Beiyishui River watershed, NCP, were analysed by a combination of multiple regression and multi‐tracer methods. The nitrate concentration of 79% of the samples exceeded the natural environmental standard of 13.3 mg l⁻¹, while that of 23% of the samples exceeded the World Health Organization (WHO) drinking water standard of 50 mg l⁻¹. Groundwater age estimation of the hill regions based on chlorofluorocarbons (CFCs) revealed a mix of young water from 1982 to 1990 and old, low CFC water. The analysis based on the variations in land use in past years revealed that part of the grassland was converted into woodland between 1980 and 1995; therefore, the land use at the recharge time was used to determine which surface conditions influence groundwater nitrate concentrations. Multiple regression analysis showed that point source pollution contributed to the high concentration of nitrate in the hill region. Fertilizer application associated with land use change from grassland to woodland was also related to the present nitrate concentration. In the plains area, the contribution of fresh water from fault fractures and denitrification led to 31 to 72% and 6 to 51% reductions in nitrate concentrations, respectively. Our results suggested that controlling point source contamination and fertilizer input to hilly regions of the study will prevent groundwater of the plains area from deterioration in future years by mixing fresh water into the aquifers and decreasing denitrification, and therefore nitrate concentrations. Copyright © 2015 John Wiley & Sons, Ltd.

In recent years, different responses of archaea and bacteria to environmental changes have attracted increasing scientific interest. In the mid-latitude region, Fen River receives water transferred from the Yellow River, electrical conductivity (EC), concentrations of Cl⁻ and Na⁺ in water, total phosphorus (TP), and Olsen phosphorus (OP) in sediments were significantly affected by water transfer. Meanwhile, temperature and oxidation-reduction potential (ORP) of water showed significant seasonal variations. Based on 16S rRNA high-throughput sequencing technology, the composition of bacteria and archaea in sediments was determined in winter and summer, respectively. Results showed that the dominance of bacterial core flora decreased and that of archaeal core flora increased after water diversion. The abundance and diversity of bacterial communities in river sediments were more sensitive to anthropogenic and naturally induced environmental changes than that of archaeal communities. Bacterial communities showed greater resistance than archaeal communities under long-term external disturbances, such as seasonal changes, because of rich species composition and complex community structure. Archaea were more stable than bacteria, especially under short-term drastic environmental disturbances, such as water transfer, due to their insensitivity to environmental changes. These results have important implications for understanding the responses of bacterial and archaeal communities to environmental changes in river ecosystems affected by water diversion.