The Greenland ice sheet is accepted as a key factor controlling the Quaternary “glacial scenario“. However, the origin and mechanisms of major Arctic glaciation starting at 3.15 Ma and culminating at 2.74 Ma are still controversial. For this phase of intense cooling Ravelo et al. [1] [A.C. Ravelo, D.H. Andreasen, M. Lyle, A.O. Lyle, M.W. Wara, Regional climate shifts caused by gradual global cooling in the Pliocene epoch. Nature 429 (2004) 263–267.] proposed a complex gradual forcing mechanism. In contrast, our new submillennial-scale paleoceanographic records from the Pliocene North Atlantic suggest a far more precise timing and forcing for the initiation of northern hemisphere glaciation (NHG), since it was linked to a 2–3 °C surface water warming during warm stages from 2.95 to 2.82 Ma. These records support previous models [G.H. Haug, R. Tiedemann, Effect of the formation of the Isthmus of Panama on Atlantic Ocean thermohaline circulation, Nature 393 (1998) 673–676. [2]] claiming that the final closure of the Panama Isthmus (3.0– ∼2.5 Ma [J. Groeneveld S. Steph, R. Tiedemann, D. Nürnberg, D. Garbe-Schönberg, The final closure of the Central American Seaway, Geology, in prep. [3]]) induced an increased poleward salt and heat transport. Associated strengthening of North Atlantic Thermohaline Circulation and in turn, an intensified moisture supply to northern high latitudes resulted in the build-up of NHG, finally culminating in the great, irreversible “climate crash” at marine isotope stage G6 (2.74 Ma). In summary, there was a two-step threshold mechanism that marked the onset of NHG with glacial-to-interglacial cycles quasi-persistent until today

The major deglacial intensification of the southwest monsoon occurred at 11,450 ± 150 calendar years before present, synchronous with a major climate transition as recorded in Greenland ice. An earlier event of monsoon intensification at 16,000 ± 150 calendar years before present occurred at the end of Heinrich layer 1 in the Atlantic and parallels the initial rise in global atmospheric methane concentrations and the first abrupt climate changes in the Antarctic; thus, the evolution of the monsoonal and high-latitude climates show teleconnections but hemispheric asymmetries. Superimposed on abrupt events, the monsoonal climate shows high-frequency variability of 1785-, 1450-, and 1150-year oscillations, and abrupt climate change seems to occur when at least two of these oscillations are in phase.

The Sr/Ca ratio of coral aragonite is used to reconstruct past sea surface temperature (SST). Twenty‐one laboratories took part in an interlaboratory study of coral Sr/Ca measurements. Results show interlaboratory bias can be significant, and in the extreme case could result in a range in SST estimates of 7°C. However, most of the data fall within a narrower range and the Porites coral reference material JCp‐1 is now characterized well enough to have a certified Sr/Ca value of 8.838 mmol/mol with an expanded uncertainty of 0.089 mmol/mol following International Association of Geoanalysts (IAG) guidelines. This uncertainty, at the 95% confidence level, equates to 1.5°C for SST estimates using Porites, so is approaching fitness for purpose. The comparable median within laboratory error is <0.5°C. This difference in uncertainties illustrates the interlaboratory bias component that should be reduced through the use of reference materials like the JCp‐1. There are many potential sources contributing to biases in comparative methods but traces of Sr in Ca standards and uncertainties in reference solution composition can account for half of the combined uncertainty. Consensus values that fulfil the requirements to be certified values were also obtained for Mg/Ca in JCp‐1 and for Sr/Ca and Mg/Ca ratios in the JCt‐1 giant clam reference material. Reference values with variable fitness for purpose have also been obtained for Li/Ca, B/Ca, Ba/Ca, and U/Ca in both reference materials. In future, studies reporting coral element/Ca data should also report the average value obtained for a reference material such as the JCp‐1.