This work mainly reviewed the classification, development, influencing factors and future prospects of solar-driven steam generation systems.

The simultaneous production of clean water and electricity using solar energy has been proposed as a promising solution to water scarcity and electricity shortage. Here, we design a thermoelectricity–freshwater cogenerator based on a thermoelectric generator (TEG) and a starch–polyacrylamide (S-PAM) hydrogel to make the maximum use of solar energy and scavenging energy. A commercial TiNO_x blue membrane with high absorptance and low emissivity covers the hot side of the TEG, which is used as the solar absorber for the main energy input. The S-PAM hydrogel underneath the cold side of TEG uses waste heat for evaporation, constituting the multistage utilization of solar energy. The temperature of the evaporation surface drops below the environmental temperature by the optimization of heat transfer channels at the cold side, resulting in a net energy gain from the environment. Simultaneously, the S-PAM hydrogel possessing a hydrophilic and porous 3D network can accommodate much water to absorb heat at the cold side of TEG during the evaporation of water, which creates a large temperature difference between the two sides of TEG and thus in turn, elevates the thermoelectricity performance. The conductive heat loss from the purifier to bulk water is fully eliminated by spraying water and the rapid heat exchange occurs at the cold side of the TEG, which results in further electricity enhancement. Due to the utilization of the scavenging energy, our hybrid cogenerator obtains an evaporation rate of 1.79 kg m⁻² h⁻¹ and a record maximum output power density of 11.39 W m⁻² during water spraying for 2 minutes under one-sun illumination in reported cogeneration systems based on TEGs. Therefore, ours is a pioneering study on a highly efficient and sustainable way to harvest solar and scavenging energy.

Wearable thermoelectric generators provide a reliable power generation method for self-powered wearable electronic devices. However, there has been a lack of research regarding the comfort of wearable thermoelectric generators. Here we propose a design for a comfortable wearable thermoelectric generators system with high output power based on sandwiched thermoelectric model. This model paves the way for simultaneously optimizing comfort (skin temperature and pressure perception) and output power by systematically considering a variety of thermal resistive environments and bending states, the properties of the thermoelectric and encapsulation materials, and the device structure. To verify this strategy, we fabricate wearable thermoelectric generators using Mg-based thermoelectric materials. These materials have great potential for replacing traditional Bi₂Te₃-based materials and enable our wearable thermoelectric generators with a power density of 18.4 μWcm⁻² under a wearing pressure of 0.8 kPa and with a skin temperature of 33 °C, ensuring the wearer’s comfort.