Studies suggest that nanometer-scale pores exist in organic matter as a result of thermal decomposition of kerogen. Depending on the host rock lithology, organic pores could be the primary storage for hydrocarbon accumulation in unconventional petroleum plays. Although various methods are publicly available, estimation of organic porosity remains a challenge because the procedures involve certain simplification or some implicit assumptions on the calculation of initial total organic carbon (TOC). In this study, we propose a revised method to address some of these issues. A model of estimating hydrocarbon expulsion efficiency is developed and incorporated into the calculation of initial TOC, thus producing an estimate of organic porosity with an improved mass balance. The method has been tested and compared with estimates using other methods based on a Rock-Eval data set in the literature. An application of the method to a large data set from the Upper Devonian Duvernay Formation petroleum system in the Western Canada Sedimentary Basin reveals that the modification has a significant effect on the estimated organic porosity. This study also indicates that organic porosity in the Duvernay Formation ranges greatly from none in immature intervals to >6% in highly mature and organic-rich shale intervals. Scanning electron microscope images of immature and mature organic-rich shale samples of the Duvernay Formation show a progressive increase in organic porosity with increasing thermal maturity, supporting the proposed model calculation. The presence of a large volume of organic porosity in mature shale intervals suggests a significant amount of hydrocarbon may be stored in the organic nanopores in the Duvernay Formation.
1 April 2018 in International Journal of Coal Geology
Canada has enormous geothermal energy resources that could supply a renewable and clean source of power. There are many constraints, however, in utilizing this energy resource, including geological, technical, and regulatory issues. The intent of this report is to examine the geothermal potential in Canada, and the geological controls on the distribution of high grade resources as well as controls on the economic development and production of geothermal energy. This assessment is based on a new compilation and digitization of data produced through over 48 years of geothermal research in Canada. Recommendations on current and future research needs to reduce barriers to resource production are made at the end of the report. Currently Canada has no geothermal electrical production; however, direct use and heat exchange systems are used widely. Several projects are currently being examined by industry and government to develop electrical potential in Canada. A key economic constraint for these projects is the high risk of exploration due to costs of deep drilling. The cost of delivered geothermal power is projected to decline and be competitive with coal fired production within the next 15 years, given current levels of technology. Canada's in-place geothermal power exceeds one million times Canada's current electrical consumption (Fig. 1). However, only a fraction of this total potential could be developed. Much of the resource lies beyond current drilling technology, outside of areas served by high-capacity transmission lines, and at some distance from load centres. Nonetheless, the available high grade geothermal resource is considerable. High temperature hydrothermal systems can be brought on line with proven technology. Many of the tools required to bring geothermal energy to full realization, however, are not commercially proven to date and require further research and technology development. We can expect a strong learning curve and price response as geothermal energy is developed while other energy sources such as coal and nuclear will begin to see fleet and capacity retirements.