Sb₂Se₃ planar solar cells with over 10.5% efficiency have been achieved by a novel additive-assisted chemical bath deposition (CBD) technology, in which the kinetics of the deposition can be elaborately regulated via the use of additives.

Antimony trisulfide (Sb₂S₃) is a kind of emerging light-harvesting material with excellent stability and abundant elemental storage. Due to the quasi-one-dimensional symmetry, theoretical investigations have pointed out that there exist complicated defect properties. However, there is no experimental verification on the defect property. Here, we conduct optical deep-level transient spectroscopy to investigate defect properties in Sb₂S₃ and show that there are maximum three kinds of deep-level defects observed, depending on the composition of Sb₂S₃. We also find that the Sb-interstitial (Sb_i) defect does not show critical influence on the carrier lifetime, indicating the high tolerance of the one-dimensional crystal structure where the space of (Sb₄S₆)_n ribbons is able to accommodate impurities to certain extent. This study provides basic understanding on the defect properties of quasi-one-dimensional materials and a guidance for the efficiency improvement of Sb₂S₃ solar cells.