In this study, four different methods for reference crop evapotranspiration (ET₀) were calibrated and validated for estimation of daily to mean monthly ET₀ by weighing lysimeter data during 2005–2006 and 2004–2005, respectively, in a semi-arid region. The value of the constant in the Hargreaves–Samani method changed from 0.0023 to 0.0026 for daily to mean monthly ET₀, and can be used in stations with only air temperature data. The constant of the aerodynamic resistance equation in the FAO-56 Penman–Monteith method (208.0) changed to 85.0. The value of coefficient a in the FAO-24-Radiation method was between −0.5 and −0.67. Further, the empirical equations were modified to estimate the value of b in the FAO-24-Radiation method and C in the FAO-24 corrected Penman method. The results showed that the modified FAO-56, corrected Penman–Monteith and FAO-24-Radiation methods are the most appropriate for estimating daily to mean monthly ET₀. Furthermore, the modified FAO-24 corrected Penman method was ranked in fourth place and its accuracy was lower than that of the other methods. However, it is appropriate for estimating mean monthly ET₀. Smoothing the daily data decreased the fluctuation in measured daily weather data and ET₀ measured by lysimeter, and consequently resulted in a higher accuracy in the estimation of daily ET₀.

Nitrogen (N) loss from irrigated cropland, especially in rice paddies, results in low N-use efficiency and groundwater contamination. Soil conditions that increase ammonium and nitrate ion retention alleviate these problems. Clinoptilolite, a naturally occurring zeolite with high-exchange capacity, may be used to absorb ammonium and retard excess leaching of nitrate. The objectives of this research were to determine the effects of different rates of Ca–K-zeolite application (0, 2, 4, and 8 g/kg soil) on pore water velocity and leaching of ammonium and nitrate applied as ammonium nitrate fertiliser to a loam soil at a rate of 350 kg N/ha under saturated conditions similar to that of a rice paddy. The results indicate that Ca–K-zeolite applications of 4 and 8 g/kg soil increase the pore water velocity by 35% and 74%, respectively. The maximum relative concentration (c/co) for the nitrate breakthrough curve occurring at pore volume of about 0.5 was reduced by 15% with a zeolite application rate of 8 g/kg soil. When applying 40 cm of leaching water, leached nitrate was 75% and 63% of total applied nitrate at the soil surface with zeolite applications of 4 and 8 g/kg soil, respectively. Due to the high ion exchange capacity of zeolite, the application of zeolite at 2 g/kg soil is enough to increase the exchange sites in the soil in order to absorb the applied ammonium and prevent its leaching by the inflow water. The maximum ammonium concentration in the breakthrough curve for the zeolite application rate of 2 g/kg soil was reduced by 43% compared with the control treatment. The relationship between the hydrodynamic dispersion coefficient (D) for nitrate and pore water velocity (v) was not linear and it was correlated with squared pore water velocity. The coefficient of the relationship between D and v2 was dependent on the zeolite application rate and linearly increased with this rate.