In order to understand the emission characteristics of volatile organic compounds (VOCs) in the flue gas under the mixed combustion of biomass, the study on the emission characteristics of VOCs in the flue gas was carried out on a 58 MW circulating fluidized bed (CFB) unit. The results show that the co-firing of biomass can significantly reduce the emissions of VOCs and NO_x and SO₂. Changes in blended fuel particle size and combustion temperature reduce VOCs emissions. The most obvious change in the emission reduction of VOCs is reflected in the increase of the biomass mixing ratio from 20 % to 30 %. Biomass contains less S and N elements is the reason for the reduction of NO_x and SO₂ emissions. The emission of pollutants such as VOCs was the lowest when the biomass blending ratio was 40 %. Based on the actual operation of the power plant, 30 % is the optimal mixing ratio. The analysis showed that the amount of VOCs components had a strong positive correlation with the proportion of biomass in the fuel. The emission of VOCs under the condition of biomass blending has different characteristics from coal-fired boilers and biomass boilers. Under the two different mixing ratios, benzene series accounted for the largest proportion of VOCs emissions, reaching 44.38 % (20 %) and 33.75 % (40 %), respectively. The emission of benzene series is dominated by benzene and toluene, the emission of alkanes is dominated by n-hexane, and the emission of esters is dominated by ethyl acetate. The ozone formation potential (OFP) was analyzed by the maximum incremental reactivity method. The contribution of ozone generation potential at 20 % and 40 % mixing ratios was mainly from benzene series, which contributed 69.88 % and 70.24 %, respectively, and alkanes. contribution can also account for 25.76 % and 17.75 %.

In order to control NOx emissions and meet China’s ultralow emission standards, a numerical simulation based on the computational fluid dynamics (CFD) approach is performed for the optimization of the reductant injection volume, number of injection sources, distribution, and injection direction for the flue gas denitrification process of a circulating fluidized bed boiler (CFB) blended with low-water content biomass in a 168 MW unit of a thermal power plant. Using the target power plant boiler entity as a template, a simplified geometric model is established, 1:1, and the mass fractions of each flue gas component set by the inlet boundary conditions are O22, H2O11.6, CO216.2%, and NO0.05%(about 134 ppm), and the reduction reactions under different optimized conditions are numerically simulated using the SNCR model in ANSYS Fluent 2021 R1. The simulation results under each condition were analyzed. The results show that the optimal ammonia-to-nitrogen ratio should be taken as NSR = 1.25, the denitrification efficiencies of 81.00, 81.63, and 82.74% at the three outlets are high, and the ammonia escapes of 1.76, 2.08, and 9.42 mg/s are within a reasonable range; increasing the number of injection sources can significantly reduce the disturbance of the flue gas flow field by reductant injection; the direction of injection is parallel to the direction of the flue gas flow, and the line of the injection source is orthogonal to the direction of the flue gas flow, which is conducive to the mixing of the reductant and flue gas; the optimized boiler denitrification efficiency reaches 74.2%, meeting the ultralow emission requirements of nitrogen oxides and ammonia escape.

Tetracycline (TC)–copper (Cu) co-contamination can impair soil functioning and intensify selection for antibiotic resistance. In a 49-day microcosm experiment, we evaluated the effects of Chlorella pyrenoidosa supplementation on soils treated with TC (0, 30, or 100 mg·kg⁻¹) and Cu (0, 100, or 500 mg·kg⁻¹). TC removal, extractable Cu, soil physicochemical properties, enzyme activities, tetracycline resistance genes (TRGs), and microbial community composition were assessed. In unamended contaminated microcosms, TC dissipation ranged from 22.7% to 43.5%, whereas C. pyrenoidosa amendment increased TC dissipation to 49.9–73.5%. The addition also reduced extractable Cu by 35.6–50.6%, partially restored dehydrogenase and catalase activities, and altered bacterial community structure. Metagenomic analysis showed that tetX was the predominant TRG detected and that algal supplementation was associated with lower total TRG signals and reduced relative abundances of several pollution-associated taxa, including Rhodanobacter. Correlation analyses revealed associations among TRGs, microbial taxa, and treatment conditions but did not establish direct host–gene relationships or horizontal gene transfer. Overall, C. pyrenoidosa application enhanced TC removal and Cu immobilization and was associated with reduced enrichment of the tetracycline resistome.