Silver (Ag) nanoparticles were synthesized by a facile route in the presence of oleic acid and n-propylamine. It was shown that the average primary size of the as-synthesized Ag nanoparticles was approximately 10 nm and the surface of as-synthesized Ag nanoparticles was capped with monolayer surfactants with the content of 19.6%. Based on as-synthesized Ag nanoparticles, polyoxymethylene (POM)/Ag nanocomposites were prepared. The influence of Ag nanoparticles on non-isothermal crystallization behavior of POM was investigated by differential scanning calorimetry (DSC). The Jeziorny, Jeziorny-modified Avrami, Ozawa, Liu and Mo, Ziabicki and Kissinger models were applied to analyze the non-isothermal melt crystallization data of POM/Ag nanocomposites. Results of half time (t1/2), crystallization rate parameter (CRP), crystallization rate function (K(T)), kinetic parameter (F(T)), the kinetic crystallizability at unit cooling rate (GZ) and the crystallization activation energy (∆E) were determined. Small amounts of Ag nanoparticles dispersed into POM matrix were shown to act as heterogeneous nuclei, which could enhance the crystallization rate of POM, increase the number of POM spherulites and reduce POM spherulites size. However, the higher loading of Ag nanoparticles were easily aggregated, which restrained POM crystallization to some degree. Furthermore, the POM/Ag nanocomposites showed robust antibacterial activity against Escherichia coli and Staphylococcus aureus.
To address the dilemma of the stiffness and toughness properties of high-density polyethylene (HDPE) composites, titanate coupling agent-treated CaCO3 nanoparticles (nano-CaCO3) and ethylene–octene copolymer (POE) were utilized to blend with HDPE to prepare ternary nanocomposites via a two-sequence-step process. Meanwhile, a one-step process was also studied as a control. The obtained ternary nanocomposites were characterized by scanning electron microscopy (SEM), Advanced Rheometrics Expansion System (ARES), Dynamic Mechanical Analysis (DMA), wide-angle X-ray diffraction analysis (WXRD), and mechanical test. The SEM results showed one or two CaCO3 nanoparticles were well-encapsulated by POE and were uniformly dispersed into the HDPE matrix to form a core–shell structure of 100–200 nm in size by the two-step process, while CaCO3 nanoparticles were aggregated in the HDPE matrix by the one-step method. The result of the XRD showed that the nano-CaCO3 particle played a role in promoting crystallization in HDPE nanocomposites. Mechanical tests showed that the synergistic effect of both the POE elastomer and CaCO3 nanoparticles should account for the balanced performance of the ternary composites. In comparison with neat HDPE, the notched impact toughness of the ternary nanocomposites of HDPE/POE/nano-CaCO3 was significantly increased. In addition, the core–shell structure absorbed the fracture impact energy and prevent further propagation of micro-cracks, thus obtaining a higher notched Izod impact strength.
An orthogonal experiment was conducted to study the effects of the aspect ratio, camber of the fore wing, and gap ratio of front and rear wing panels on the hydrodynamic performance of double-vane otter boards. The design of the orthogonal experiment comprised three factors (each having three levels), namely the aspect ratio (1.0, 1.5, and 2.0), camber (0.12, 0.14, and 0.16), and gap ratio (0.25, 0.30, and 0.35), the drag coefficient Cx and the lift coefficient Cy of nine otter board models obtained in a wind tunnel experiment, and the lift–drag ratio K obtained by calculation. The lift–drag ratio for a working angle of attack of 30° was selected as the inspection index, and the experimental data were analyzed in an orthogonal design-direct analysis. Analysis of each factor revealed that the optimal level combination of factors was A3B3C3 and that the decreasing order of the effects of the factors was A (aspect ratio) > B (gap ratio) > C (camber). The orthogonal experiment thus obtained an optimal otter board in terms of the aspect ratio (2.0), fore wing camber (0.16), and gap ratio (0.35), with the aspect ratio having the greatest effect on performance. The hydrodynamic performances of the otter board with the optimized structure and another otter board model were compared in numerical simulation, which verified the correctness of the analysis results. The experimental results provide a reference for the optimal design of the double-vane otter board.
The effect of panel shape on hydrodynamic performances of a vertical v-shaped double-slotted cambered otter-board was investigated using engineering models in a wind tunnel. Three different shape panels (rhomboid, left trapezoid and isosceles trapezoid) were evaluated at a wind speed of 28 m/s. Parameters measured included: drag coefficient Cx, lift coefficient Cy, pitch moment coefficient Cm, center of pressure coefficient Cp , over a range of angle of attack (0° to 70°). These coefficients were used in analyzing the differences in the performance among the three otter-board models. Results showed that the maximum lift coefficient Cy of the otter-board model with the isosceles trapezoid shape panels was highest (2.103 at α=45°). The maximum Cy/Cx of the otter-board with the rhomboid shape panels was highest (3.976 at α=15°). A comparative analysis of Cm and Cp showed that the stability of otter-board model with the isosceles trapezoid shape panels is better in pitch, and the stability of otter-board model with the left trapezoid shape panels is better in roll. The findings of this study can offer useful reference data for the structural optimization of otter-boards for trawling.
The effect of deflector angle on hydrodynamic performances of a double-slotted cambered otter-board is investigated using engineering models in a wind tunnel. Three different angle combinations (35°-30°, 30°-25°and 25°-20°) are evaluated at a wind speed of 28 m/s. Parameters measured included: drag coefficient Cx, lift coefficient Cy, pitch moment coefficient Cm, center of pressure coefficient Cp, over a range of angle of attack (0° to 70°). These coefficients are used in analyzing the differences in the performance among the three otter-board models. Results shows that the maximum lift coefficient Cy of the otter-board model with the angle combination (35°-30°) of two deflectors is the highest (2.160 at a=55°). The maximum Cy/Cx of the otter-board with the angle combination (25°-20°) is the highest (3.842 at a=2.5°). A comparative analysis of Cm and Cp shows that the stability of otter-board model with the angle combination (25°-20°) is better in pitch, and the stability of otter-board model with the angle combination (30°-25°) is better in roll. The findings of this study can offer useful reference data for the structural optimization of otter-boards for trawling.
The effect of deflector curvature on hydrodynamic performances of a double-slotted cambered otter-board was investigated using engineering models in a wind tunnel. Four different curvature (0.06,0.09, 0.12 and 0.15) were evaluated at a wind speed of 28 m/s. Parameters measured included: drag coefficient Cx, lift coefficient Cy, pitch moment coefficient Cm, center of pressure coefficient Cp , over a range of angle of attack (0° to 70°). These coefficients were used in analyzing the differences in the performance among the four otter-board models. Results showed that the maximum lift coefficient Cy of the otter-board model with the curvature (0.06) of two deflectors was highest (2.020 at °=55°). The maximum Cy/Cx of the otter-board with the curvature (0.12) of two deflectors was highest (3.655 at °=22.5°). A comparative analysis of Cm and Cp showed that the stability of otter-board model with the curvature (0.12) of two deflectors is better in pitch, and the stability of otter-board model with the curvature (0.06) of two deflectors is better in roll. The findings of this study can offer useful reference data for the structural optimization of otter-boards for trawling.