Flexible supercapacitors (FSCs) are limited in flexible electronics applications due to their low energy density. Therefore, developing electrode materials with high energy density, high electrochemical activity, and remarkable flexibility is challenging. Herein, we designed nitrogen-doped porous MXene (N-MXene), using melamine-formaldehyde (MF) microspheres as a template and nitrogen source. We combined it with an electrospinning process to produce a highly flexible nitrogen-doped porous MXene nanofiber (N-MXene-F) as a self-supporting electrode material and assembled it into a symmetrical supercapacitor (SSC). On the one hand, the interconnected mesh structure allows the electrolyte to penetrate the porous network to fully infiltrate the material surface, shortening the ion transport channels; on the other hand, the uniform nitrogen doping enhances the pseudocapacitive performance. As a result, the as-assembled SSC exhibited excellent electrochemical performance and excellent long-term durability, achieving an energy density of 12.78 Wh kg⁻¹ at a power density of 1080 W kg⁻¹, with long-term cycling stability up to 5000 cycles. This work demonstrates the impact of structural design and atomic doping on the electrochemical performance of MXene and opens up an exciting possibility for the fabrication of highly FSCs.

Using renewable H₂ for CO₂ hydrogenation to methane not only achieves CO₂ utilization, but also mitigates the greenhouse effect. In this work, several Ni-based catalysts with V species using 3D-mesoporous KIT-6 (Korea Advanced Institute of Science and Technology, KIT) as support were prepared at different contents of NiO and V₂O₅. Small Ni nanoparticles with high dispersibility on 20Ni-0.5V/KIT-6 were identified by X-ray diffraction (XRD), TEM and hydrogen temperature-programmed desorption (H₂-TPD) analysis, which promoted the production of more Ni active sites for enhancing catalytic activity for CO₂ methanation. Moreover, TEM and hydrogen temperature-programmed reduction (H₂-TPR) characterizations confirmed that a proper amount of Ni and V species was favorable to preserve the 3D-mesoporous structure and strengthen the interaction between active Ni and KIT-6. The synergistic effect between Ni and V could strengthen surface basicity to elevate the ability of CO₂ activity on the 20Ni-0.5V/KIT-6. In addition, a strong interaction with the 3D-mesoporous structure allowed active Ni to be firmly anchored onto the catalyst surface, which was accountable for improving catalytic activity and stability. These results revealed that 20Ni-0.5V/KIT-6 was a catalyst with superior catalytic activity and stability, which was considered as a promising candidate for CO₂ hydrogenation to methane.

Antibiotic overuse poses a serious food safety problem. Therefore, it is of great importance to develop efficient assays that respond to antibiotics to establish early-warning mechanisms. Here, we prepared a three-dimensional (3D) porous reduced graphene oxide (pRGO) modified electrode, which was characterized by scanning electron microscopy and transmission electron microscopy. As a result of the introduction of the 3D pRGO film, the electrocatalytic activity was considerably improved, which could efficiently trigger the redox reaction of rifampicin (RIF). By employing differential pulse voltammetry, the reduction peak current of RIF showed a good linear relationship with the logarithm of the RIF concentration in the range 1.0 × 10⁻⁹ to 1.0 × 10⁻⁷ mol L⁻¹. The linear equation was i_p (−10⁻⁶ A) = 3.11 + 0.28 log c_RIF (R² = 0.9908) with a detection limit of 2.7 × 10⁻¹⁰ mol L⁻¹ (S/N = 3). Additionally, the final electrode displayed long stability, good reproducibility and high selectivity, and could detect trace RIF in milk with satisfactory results. This study reveals the great potential in utilizing 3D pRGO to develop efficient electrochemical sensors for safeguarding food safety.