Oxide thin-film transistors (TFTs) with high mobility and excellent stability are extremely desired for advanced displays. In this work, we simultaneously enhanced the mobility and stability of In2O3 TFTs by nitrogen modification strategy, and systematically investigated the effects of nitrogen doping content on the structures and properties of In2O3 films and the TFT performance. With increasing amount of the nitrogen flow rate from 0 to 9 SCCM, crystallinity and surface quality are improved, while the oxygen defect, optical bandgap, and Urbach energy are decreased, gradually. At a suitable nitrogen flow rate of 6 SCCM, In2O3 films exhibit optimal comprehensive properties, such as high crystallinity, low surface roughness, and defect density, yielding significant enhancement in TFT performance. In particular, the N modified In2O3 TFT demonstrates a highest mobility of 24.96 cm2/V s, accompanied by superior positive and negative bias stability. And then, degradation mechanisms of the TFT stabilities are comprehensively revealed. The findings may be generalizable to other oxide electronics.
Metal-oxide thin-film transistors (TFTs) are promising for next-generation display backplanes and large-area electronics, while single-channel oxide TFTs often suffer from trade-offs among mobility, leakage current, and switching behavior. Here, an In2O3/SnO2 dual-channel TFT was fabricated by magnetron sputtering to combine the high electron transport capability of In2O3 with the leakage-suppression characteristics of SnO2. Compared with single-layer In2O3, single-layer SnO2, and reverse-stacked SnO2/In2O3 devices, the optimized In2O3/SnO2 TFT exhibits improved overall performance, with a linear mobility of 19.15 cm2/Vs, a subthreshold swing of 0.86 V/dec, an on/off current ratio of 3.58 × 106 and an optimized threshold voltage. The mobility is approximately 2.2 times higher than that of the single-layer In2O3 TFT, accompanied by obviously enhanced positive and negative stress stabilities. Furthermore, structural, chemical and optical analyses indicate that the enhanced performance can be attributed to the smooth heterointerface, favorable band alignment, and interfacial carrier redistribution between In2O3 and SnO2. The superior performance highlights the potential of the In2O3/SnO2 bilayer architecture for high-performance display-backplane switching and other large-area oxide-electronics applications.
SnO2 exhibits low cost, high electron mobility and good optical transparency, making it a promising candidate for the active layer of indium-free oxide thin-film transistors (TFTs). However, its film qualities are highly sensitive to deposition conditions. In this work, SnO2 thin films and TFTs were fabricated by radio-frequency magnetron sputtering under different substrate biases (0 V, −70 V and −110 V) to investigate the effects of substrate bias on film structure, defect state, interface quality and device performance. With increasing substrate bias magnitude, the film crystallinity improved, the relative area fraction of the defect-related O 1s component decreased from 31% to 19%, while the surface roughness increased, continuously. At a substrate bias of −70 V, the device exhibited relatively optimal overall performance, with a linear mobility (μlin) of 3.7 cm2/Vs, a subthreshold swing (SS) of 0.61 V/dec, and a threshold-voltage shift (ΔVth) of 6.0 V after 3600 s of positive bias stress. These results indicate that an appropriate substrate bias can achieve a balance between crystalline quality and interface condition, thereby improving the performance of SnO2 TFTs.