Graphitic carbon nitride (g-C3N4) nanosheets loaded with WO3 nanoparticles were prepared via heat treatment of g-C3N4 together with WOx-EDA nanobelts. The thermal treatment temperature and WOx-EDA precursor play the key role in enhancing the interaction between WO3 nanoparticles and g-C3N4 nanosheets, because the temperature of thermal decomposition of WOx-EDA (∼400 °C) is close to the thermal exfoliation temperature of g-C3N4. The structure evolution and promotion effect of the nanocomposites in photocatalytic performance were well studied. It is found that WO3 nanoparticles uniformly dispersed on the surface of the g-C3N4 nanosheets, and the close integration of WO3 and g-C3N4 lead to the high photocatalytic activity in the degradation of RhB under visible light irradiation. Meanwhile, a larger specific area and increase of visible light absorption are also of benefit to speed up the degradation of organic dye. Also, the mechanism of the photocatalytic reaction and its reutilization properties were investigated.
Oxidation behaviors of three Ni-based model alloys and pure Ni in the temperature range of 700–1200 °C are investigated to reveal effects of Cr, Al, and Si on the oxidation resistance of Ni-based superalloys. The formation and integrity of consecutive chromia or alumina layers are important for excellent oxidation resistance. The addition of 20 at.% Cr can effectively improve the oxidation resistance of Ni-based alloys by forming a thin chromia film below 1000 °C, while adding 15 at.% Al has a beneficial effect on the oxidation resistance of Ni-based alloys at temperatures above 900 °C. The addition of 2 at.% Si to Ni-Al alloy is insufficient to form a protective SiO2 layer but can accelerate the formation of alumina, which enables Ni-Al alloy to form a consecutive inner alumina layer at a relatively low temperature of 800 °C and further improve the oxidation resistance above 800 °C.
Single-crystalline bismuth-layered perovskite Bi4Ti3O12 nanosheets with a thickness of about 20 nm and a lateral size over several micrometers have been synthesized by a PVA assisted hydrothermal route. The as-prepared Bi4Ti3O12 nanosheets were characterized by means of X-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy (TEM) and high-resolution TEM. The as-prepared Bi4Ti3O12 nanosheets have (010) dominated surface facets. Time-dependent experiments reveal that the layered K2Ti6O13 nanofibers formed in the initial stage of the hydrothermal treatment play a key role in the synthesis of Bi4Ti3O12. In the proceeding hydrothermal treatment, the Bi3+ ions substitute for the K+ ions in the layered K2Ti6O13 and peel off the TiO6 octahedron lamellae from the lattice of K2Ti6O13, which then serves as a template for the formation of lamellar Bi4Ti3O12 by reaction with the dehydrated Bi3+ ions. Finally, the lamellar Bi4Ti3O12 species crystallize and grow to single-crystalline Bi4Ti3O12 nanosheets under the effect of the preferential adsorption of PVA on the (010) planes. In addition, the band gap and the optoelectronic properties of the single-crystalline Bi4Ti3O12 nanosheets were investigated by measuring their UV-vis absorption and photoluminescence spectra, respectively.
Single-crystal strontium titanate (SrTiO3) nanosheets have been synthesized via a solvothermal reaction route with ethylene glycol (EG) as reaction medium solvent. The as-synthesized SrTiO3 products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and high resolution transmission electron microscopy, respectively. The results show that the single-crystal SrTiO3 nanosheets are parallel to the (110) plane and self-assembled by primary nanocrystallites in monolayer. EG as a organic solvent plays an important role in the synthesis of the single-crystal SrTiO3 nanosheets. Based on the experimental results, a possible formation mechanism of the single-crystal SrTiO3 nanosheets has been proposed.