The environment is fundamental to human existence, and protecting it from dangerous contaminants should be a top priority for all stakeholders. Reducing garbage output has helped, but as the world's population grows, more waste will be generated. Tons of waste inadvertently and advertently received by environmental matrixes adversely affect the sustainable environment. The pollution caused by these activities affects the environment and human health. Conventional remediation processes ranging from chemical, physical, and biological procedures use macroaggregated materials and microorganisms to degrade or remove pollutants. Undesirable limitations of expensiveness, disposal challenges, maintenance, and formation of secondary contaminants abound. Additionally, multiple stages of treatments to remove different contaminants are time-consuming. The need to avoid these limitations and shift towards sustainable approaches brought up nanotechnology options. Currently, nanomaterials are being used for environmental rejuvenation that involves the total degradation of pollutants without secondary pollution. As nanoparticles are primed with vast and modifiable reactive sites for adsorption, photocatalysis, and disinfection, they are more useful in remediating pollutants. Review articles on metallic nanoparticles usually focus on chemically synthesized ones, with a particular focus on their adsorption capacity and toxicities. Therefore, this review evaluates the current status of biogenic metallic nanoparticles for water treatment and purification.

Copper is a non-biodegradable heavy metal, and high levels in water bodies cause serious environmental and health issues. Douglas fir biochar has a higher number of carboxylic, phenolic, and lactonic groups, which provide suitable active sites for copper removal. Douglas fir biochar (BC) was modified using 20% solutions of KOH (KOH/BC), H₂SO₄, (H₂SO₄/BC), and Na₂CO₃ (Na₂CO₃/BC). All materials were characterized using SEM, SEM-EDS, FTIR, TGA, XRD, BET, and elemental analysis. These modifications were done to compare the activations of those sites by measuring copper removal efficiencies. KOH/BC, H₂SO₄/BC, and Na₂CO₃/BC materials gave surface areas of 389.3, 326.7, and 367.9 m² g⁻¹, respectively, compared with pristine biochar with a surface area of 578.9 m² g⁻¹. The maximum Langmuir adsorption capacities for Na₂CO₃/BC, KOH/BC, BC, and H₂SO₄/BC were 24.79, 18.31, 17.38, and 9.17 mg g⁻¹, respectively. All three modifications gave faster kinetics at 2 mg/L initial copper concentrations (pH 5) compared with pristine BC. The copper removal efficiency was demonstrated in four different spiked real water matrices. The copper removals of all four water matrices were above 90% at 2 mg/L initial concentration with a 2 g/L biochar dosage. The competitive effects of Pb²⁺, Zn²⁺, Cd²⁺, and Mg²⁺ were studied at equimolar concentrations of Cu²⁺ and competitive ions for all four materials.