We describe the synthesis and characterization of a new tetradentate Schiff base ligand obtained from 2,3-diaminopyridine and 5-methoxysalicylaldehyde. This ligand (H₂L) reacted with nickel(II), copper(II), and zinc(II) acetates to give complexes. The ligand and its metal complexes were characterized using analytical, spectral data (UV–vis, IR, and mass spectroscopy), and cyclic voltammetry (CV). The crystal structure of the copper complex was elucidated by X-ray diffraction studies. The electrochemical behavior of these compounds, using CV, revealed that metal centers were distinguished by their intrinsic redox systems, e.g. Ni(II)/Ni(I), Cu(II)/Cu(I), and Zn(II)/Zn(I). Moreover, the electrocatalytic reactions of Ni(II) and Cu(II) complexes catalyze the oxidation of methanol and benzylic alcohol.

In this study, the modification of glassy carbon electrodes by potentiostatic pulsed deposition of platinum nanoparticles and potentiostatic pulsed polymerization of polyaniline nanofibers was investigated. During the preparation of the nano-composite materials, the control of the potentiostatic pulsed deposition and potentiostatic pulsed polymerization parameters, such as pulse potential, pulse width time, duty cycle, and platinum precursor concentration allowed the optimization of the size, shape, and distribution of the deposited Pt nanoparticles. It is noteworthy that the polymerization method, cyclic voltammetry method, or potentiostatic pulsed polymerization method show an important effect in the morphology of the deposited polyaniline (PANI) film. The obtained modified electrodes, with highly uniform and well dispersed platinum nanoparticles, exhibit good electrocatalytic properties towards methanol oxidation.

This work describes the synthesis of a new unsymmetrical tetradentate copper(ii) Schiff base complex Cu(L)(Py)(ClO4) containing N₃O donor atoms.