Fuel cells are an important source of renewable energy technology and currently the subject of much research. Hydrogen gas, which is the main fuel source in fuel cells, is relatively easily available, and the exhaust does not consist of greenhouse gases, unlike fossil fuel-based power sources. Some of the challenges persisting in fuel cell technology are the cost of the fuel cell due to factors such as platinum catalyst loading and water management. This study reviews the use of carbon nanotubes (CNTs) in fuel cell applications. CNTs have a large number of superior properties, including electrical conductivity, thermal conductivity, mechanical strength, and ability to support catalysts by providing an increased surface area. Carbon nanotubes offer great promise for overcoming the problems of existing fuel cells. However, they still pose challenges of functionalization on components of the polymer electrolyte membrane fuel cell (PEMFC), namely the membrane electrode assembly (MEA), the gas diffusion layer (GDL), and the bipolar plates. This paper discusses various experimental techniques that have achieved success in this functionalization process. Application of CNTs in fuel cells is expected to improve fuel cell performance and efficiency and bring down the cost by reducing platinum (Pt) catalyst loading
20 December 2024 in International Journal of Thermal Sciences
A porous iron oxide nanolayer coating is grown on LiMn2O4 by a facile in‐situ method. Evolution of this coating and its influence on the structural retention and electrochemical activity of LiMn2O4 is examined and compared to a control in the environment of an aqueous rechargeable lithium‐ion battery. Two coinciding mechanisms of porous iron oxide nanolayer deposition and their depency on electrolyte pH are identified and discussed. The coating is found to significantly reduce Li2MnO3 surface formation, a major source of capacity fade in LiMn2O4 electrodes, thereby improving the structural retention. The nanolayer was also found to improve the electrochemical stability of the underlying LiMn2O4 in the potential window of lithium intercalation, reduce the growth rate of mass transfer and solid electrolyte interface resistances over the control, while also providing reduced charge transfer resistances over the pristine LiMn2O4 material. The totality of these improvements provided by the porous iron oxide nanolayer preserved the electrochemical and structural integrity of LiMn2O4 over the course of 500 deep discharge cycles in aqueous media.
18 August 2015 in International Journal of Energy Research