By taking advantage of the elevation domain, three-dimensional (3-D) multiple input and multiple output (MIMO) with massive antenna elements is considered as a promising and practical technique for the fifth Generation mobile communication system. So far, 3-D MIMO is mostly studied by simulation and a few field trials have been launched recently. It still remains unknown how much does the 3-D MIMO meet our expectations in versatile scenarios. In this paper, we answer this based on measurements with 56 × 32 antenna elements at 3.5 GHz with 100-MHz bandwidth in three typical deployment scenarios, including outdoor to indoor (O2I), urban microcell (UMi), and urban macrocell (UMa). Each scenario contains two different site locations and 2-5 test routes under the same configuration. Based on the measured data, both elevation and azimuth angles are extracted and their stochastic behaviors are investigated. Then, we reconstruct two dimensional and 3-D MIMO channels based on the measured data, and compare the capacity and eigenvalues distribution. It is observed that 3-D MIMO channel which fully utilizes the elevation domain does improve capacity and also enhance the contributing eigenvalue number. However, this gain varies from scenario to scenario in reality, O2I is the most beneficial scenario, then followed by UMi and UMa scenarios. More results of multiuser capacity varying with the scenario, antenna number and user number can provide the experimental insights for the efficient utilization of 3-D MIMO in future.

Herein, polylactic acid cast films were prepared with different melt-draw ratios via an extrusion casting process. The structure and properties of the prepared films were characterized. The results showed that with the increasing melt-draw ratios (MDRs), an oriented structure appeared at first, and then, a chi structure crystal was formed at higher MDRs. The vertical shish crystals showed a higher melting point than the oriented structure. The PLA molecules were extended by melt-stretching, and weak hydrogen bonds appeared between the carbonyl and methyl bond in the neighbourhood extended PLA molecular chain segments. The hydrogen bond limited the molecular mobility in the amorphous region, which increased the weight fraction of the rigid amorphous region. The stretching-induced crystallization occurred during the melt-stretching process, but the formed crystals were not strictly α form or α′ form. At lower MDRs, mainly an oriented structure was formed, and with the increase in MDR, meridional streaks in SAXS patterns appeared, accompanying the shish formation. The kebab and oriented structure signals superimposed together; this led to irregular equatorial scattering patterns. In this study, we provide a new insight into PLA crystallization via melt-extrusion cast flow.

In order to study the effect of interfacial wettability of separator on electrochemical properties for lithium–ion batteries, two different kinds of polyvinylidene fluoride-hexafluoropropylene (PVDF–HFP) solution are prepared and used to coat onto a polypropylene (PP) microporous membrane. It is found that the cell performance of a coated separator using aqueous slurry (WPS) is better than that of the coated separator using acetone (APS) as the solvent. The separator with flat and pyknotic surface (PP and APS) has a strong polar action with the electrolyte, where the polar part is more than 80%. To the contrary, the WPS has a roughness surface and when the PVDF–HFP particles accumulate loose, it makes the apolar part plays a dominate role in surface free energy; the dispersive energy reaches to 40.17 mJ m⁻². The WPS has the lowest immersion free energy, 31.9 mJ m⁻² with the electrolyte, and this will accelerate electrolyte infiltration to the separator. The loose particle accumulation also increases the electrolyte weight uptake and interfacial wettability velocity, which plays a crucial role in improving the cell performance such as the ionic conductivity, discharge capacity and the C-rate capability.

A series of novel modified waterborne polyurethane acrylate (WPU-EA) emulsions were prepared with isophorone diisocyanate (IPDI), polycarbonate diol, 2,2-bis-hydroxymethyl-propionic acid (DMPA), 1,4-butanediol (BDO), epoxy acrylate (EA), and pentaerythritol triacrylate (PETA). The structure of WPU-EA was confirmed by FTIR and ¹H NMR spectroscopy. The effects of different dosages of epoxy acrylate on the cured film were investigated by tensile properties, dynamic mechanical analysis and thermogravimetric analysis. The results indicate that with increasing content of epoxy acrylate, the average particle size of the emulsion gradually increases. With the rise in epoxy acrylate concentration from 0%, 3.0%, 6.0% to 9.0%, the gel fraction of the cured film increases from 83.7%, 92.5%, 93.0% to 93.6%, respectively, and the glass transition temperature rises from 90.3 °C, 107.5 °C, 141.9 °C to 146.6 °C. The tensile strength and the thermal stability of the cured film increases, and the elongation at break decreases. Moreover, the WPU-EA emulsions were sprayed on polycarbonate sheets and exhibited the advantages of high hardness, better gloss and good adhesion, which is promising for the application of plastic coatings.