The problems of developing intelligent service provision systems face difficulties in the representation of dynamic aspects of cargo transportation processes and integration of different and heterogeneous ICT components to support the systems’ necessary functionality. This research aims to develop the architecture of the e-service provision system that can help in traffic management, coordination of works at trans-shipment terminals, and provide intellectual service support during intermodal transportation cycles. The objectives concern the secure application of the Internet of Things (IoT) technology and wireless sensor networks (WSNs) to monitor transport objects and context data recognition. The means for safety recognition of moving objects by integrating them with the infrastructure of IoT and WSNs are proposed. The architecture of the construction of the e-service provision system is proposed. The algorithms of identification, authentication, and safety connection of moving objects into an IoT platform are developed. The solution of application of blockchain mechanisms for the identification of stages of identification of moving objects is described by analysing ground transport. The methodology combines a multi-layered analysis of intermodal transportation with extensional mechanisms of identification of objects and methods of synchronization of interactions between various components. Adaptable e-service provision system architecture properties are validated during the experiments with NetSIM network modelling laboratory equipment and show their usability.