Fluorescent nanoclusters are an emerging class of modular nanomaterials. This review highlights recent developments in tailoring the photo-luminescence of nanoclusters.

Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles, providing unique opportunities for investigating the quantum effects and precise structure–property correlations at the atomic level. As a versatile strategy, alloying can largely improve the physicochemical performances compared to the corresponding homo-metal nanoclusters, and thus benefit the applications of such nanomaterials. In this review, we highlight the achievements of atomically precise alloy nanoclusters, and summarize the alloying principles and fundamentals, including the synthetic methods, site-preferences for different heteroatoms in the templates, and alloying-induced structure and property changes. First, based on various Au or Ag nanocluster templates, heteroatom doping modes are presented. The templates with electronic shell-closing configurations tend to maintain their structures during doping, while the others may undergo transformation and give rise to alloy nanoclusters with new structures. Second, alloy nanoclusters of specific magic sizes are reviewed. The arrangement of different atoms is related to the symmetry of the structures; that is, different atoms are symmetrically located in the nanoclusters of smaller sizes, and evolve into shell-by-shell structures at larger sizes. Then, we elaborate on the alloying effects in terms of optical, electrochemical, electroluminescent, magnetic and chiral properties, as well as the stability and reactivity via comparisons between the doped nanoclusters and their homo-metal counterparts. For example, central heteroatom-induced photoluminescence enhancement is emphasized. The applications of alloy nanoclusters in catalysis, chemical sensing, bio-labeling, and other fields are further discussed. Finally, we provide perspectives on existing issues and future efforts. Overall, this review provides a comprehensive synthetic toolbox and controllable doping modes so as to achieve more alloy nanoclusters with customized compositions, structures, and properties for applications. This review is based on publications available up to February 2020.

Au ₂₅ (SR) ₁₈ , as the captain of the great nanocluster ship, is capable of reviewing the history and guiding the future of the nanoclusters.

Endowing three-dimensional (3D) displays with flexibility drives innovation in the next-generation wearable and smart electronic technology. Printing circularly polarized luminescence (CPL) materials on stretchable panels gives the chance to build desired flexible stereoscopic displays: CPL provides unusual optical rotation characteristics to achieve the considerable contrast ratio and wide viewing angle. However, the lack of printable, intense circularly polarized optical materials suitable for flexible processing hinders the implementation of flexible 3D devices. Here, we report a controllable and macroscopic production of printable CPL-active photonic paints using a designed confining helical co-assembly strategy, achieving a maximum luminescence dissymmetry factor ( g _lum ) value of 1.6. We print customized graphics and meter-long luminous coatings with these paints on a range of substates such as polypropylene, cotton fabric, and polyester fabric. We then demonstrate a flexible textile 3D display panel with two printed sets of pixel arrays based on the orthogonal CPL emission, which lays an efficient framework for future intelligent displays and clothing.