We report exciton-polariton condensation in a new family of fully hybrid ZnO-based microcavity demonstrating the best-quality ZnO material available (a bulk substrate), a large quality factor ($$\sim${}4000$) and large Rabi splittings ($$\sim${}240\text{\,}\text{\,}\mathrm{meV}$). Condensation is achieved between 4 and 300~K and for excitonic fractions ranging between 17% and 96%, which corresponds to a tuning of the exciton-polariton mass, lifetime, and interaction constant by 1 order of magnitude. We demonstrate mode switching between polariton branches allowing, just by controlling the pumping power, to tune the photonic fraction by a factor of 4.

A ZnO planar optical microcavity displaying room-temperature polariton lasing over a wide range of cavity-exciton detunings has been fabricated. The cavity combines optimum crystalline quality, given by a ZnO single-crystal substrate, and optimum photonic quality, obtained by the use of two dielectric SiO2/HfO2 Bragg mirrors. A maximum cavity quality factor of about 4000 has been measured. Typically, the polariton lasing transition is accompanied by an increase of the output intensity by more than two orders of magnitude, a reduction of the emission linewidth and a relatively small blueshift of the lower polariton branch (less than 5% of the Rabi splitting).