Carbamazepine (CBZ), one of the most used pharmaceuticals worldwide and a Contaminant of Emerging Concern, represents a potential risk for the environment and human health. Wastewater treatment plants (WWTPs) are a significant source of CBZ to the environment, polluting the whole water cycle. In this review, the CBZ presence and fate in the urban water cycle are addressed, with a focus on adsorption as a possible solution for its removal. Specifically, the scientific literature on CBZ removal by activated carbon and its possible substitute Biochar, is comprehensively scanned and summed up, in view of increasing the circularity in water treatments. CBZ adsorption onto activated carbon and biochar is analyzed considering several aspects, such as physicochemical characteristics of the adsorbents, operational conditions of the adsorption processes and adsorption kinetics and isotherms models. WWTPs usually show almost no removal of CBZ (even negative), whereas removal is witnessed in drinking water treatment plants through advanced treatments (even >90%). Among these, adsorption is considered one of the preferable methods, being economical and easier to operate. Adsorption capacity of CBZ is influenced by the characteristics of the adsorbent precursors, pyrolysis temperature and modification or activation processes. Among operational conditions, pH shows low influence on the process, as CBZ has no charge in most pH ranges. Differently, increasing temperature and rotational speed favor the adsorption of CBZ. The presence of other micro-contaminants and organic matter decreases the CBZ adsorption due to competition effects. These results, however, concern mainly laboratory-scale studies, hence, full-scale investigations are recommended to take into account the complexity of the real conditions.

Biochar has been used in various applications, e.g., as a soil conditioner and in remediation of contaminated water, wastewater, and gaseous emissions. In the latter application, biochar was shown to be a suitable alternative to activated carbon, providing high treatment efficiency. Since biochar is a by-product of waste pyrolysis, its use allows for compliance with circular economics. Thus, this research aims to obtain a detailed characterization of three carbonaceous materials: an activated carbon (CARBOSORB NC 1240^®) and two biochars (RE-CHAR^® and AMBIOTON^®). In particular, the objective of this work is to compare the properties of three carbonaceous materials to evaluate whether the application of the two biochars is the same as that of activated carbon. The characterization included, among others, particle size distribution, elemental analysis, pH, scanning electron microscope, pore volume, specific surface area, and ionic exchange capacity. The results showed that CARBOSORB NC 1240^® presented a higher specific surface (1126.64 m²/g) than AMBIOTON^® (256.23 m²/g) and RE-CHAR^® (280.25 m²/g). Both biochar and activated carbon belong to the category of mesoporous media, showing a pore size between 2 and 50 nm (20–500 Å). Moreover, the chemical composition analysis shows similar C, H, and N composition in the three carbonaceous materials while a higher O composition in RE-CHAR^® (9.9%) than in CARBOSORB NC 1240 ^® (2.67%) and AMBIOTON^® (1.10%). Differences in physical and chemical properties are determined by the feedstock and pyrolysis or gasification temperature. The results obtained allowed to compare the selected materials among each other and with other carbonaceous adsorbents.

Chemical precipitation with the addition of ferric chloride is commonly used to remove phosphorous from wastewater. However, since its application involves also several disadvantages, studying alternative solutions is required. The present paper shows the results of a full-scale experimental work aimed at evaluating the efficiency of the ion exchange process using a polymeric anion exchange resins impregnated with aluminum ions in the removal of phosphorous from wastewater. The study compared the results obtained through this process with chemical precipitation, considering both technical and economic issues. At the same dosage of 6 L/h and influent concentration (about 6 mg/L), total removal efficiency of 95% and 78% (including also that occurring in the mechanical and biological processes) were achieved by means of the anion exchange process and chemical precipitation, respectively. However, in the latter case, this value was insufficient to ensure consistent compliance with the limit of 2 mg/L P_tot set on the effluent; to achieve this goal, ferric chloride dosage had to be risen up to 12 L/h, thus increasing the related costs. Furthermore, the anion exchange process generated a lower sludge production. Therefore, it showed to represent a valid alternative to chemical precipitation for P removal from wastewater.