Microstructure, mechanical properties, wear resistance, corrosion and corrosive wear resistance of AlCrFeNiWx (x = 0, 0.1, 0.2, 0.3 and 0.4) medium-entropy alloys (MEAs) prepared by vacuum arc melting process were investigated. Results of the study show that the microstructure of as-cast AlCrFeNiWx alloys is composed of one disordered Fe-Cr rich BCC phase (A2) and one ordered NiAl-rich (B2) phase when x = 0 and 0.1; W particles appear when x ≥ 0.2. Hardness and strength of AlCrFeNi alloy are markedly increased by the W addition. The strengthening mechanisms include solid-solution strengthening, nano-sized precipitation strengthening and second phase strengthening. The excellent ductility of AlCrFeNi is retained with minor W addition (x ≤ 0.2) but it considerably declines as more W is added, resulting from the precipitation of excessive large-sized W particles. W addition improves the pitting resistance and passivation property of AlCrFeNi HEA in 3.5 wt. % NaCl solution. It is shown that AlCrFeNiW0.3 possesses the highest corrosion resistance, as reflected by the highest Ecorr and the lowest Icorr. Tungsten notably enhances the resistance of this HEA to wear and corrosive wear. AlCrFeNiW0.4 with the highest strength and hardness exhibits the lowest wear volume loss under both dry and corrosive wear conditions.
The addition of third elements may help transform brittle D022-structured lightweight Al3Ti to a relatively ductile L12-structured (Al, M)3Ti (where M represents the third elements), thus increasing the ductility at the expense of hardness. Such a transformation could benefit the wear resistance of the alloy due to improved toughness if a proper balance between the hardness and ductility is achieved. In this work, a D022-predominant Al3Ti alloy (S-Al3Ti) and an L12-predominant (Al, Fe)3Ti alloy (S-Al67Ti25Fe8) were fabricated by arc melting. Change in wear resistance, corresponding to a D022-to-L12 transformation, caused by the addition of Fe as a representative third element, was investigated and compared with the wear resistance of a commercial Al-matrix composite reinforced by 30 wt.% SiC particles (S-Al/SiCp) as a reference material. It was observed that wear of the S-Al3Ti resulted from abrasion involving synergistic oxidation, leading to a larger volume loss. In contrast, the softer S-Al67Ti25Fe8 showed enhanced wear resistance, benefiting from improved toughness with reasonable hardness. During the wear testing, both the alloys exhibited better performance than S-Al/SiCp, a well-known lightweight composite. This study highlights that D022-to-L12 transformation enhances wear resistance due to increased toughness which can be adjusted using the addition of a third element.
13 March 2017 in Industrial Lubrication and Tribology
Purpose: This paper aims to clarify the friction properties of 304 steel surface modification. The surface modification includes laser texturing processing and nitriding treatment on 304 steel surface, and then the friction properties’ test was conducted on different friction directions and different upper test samples by using microfriction and wear testing machine. Design/methodology/approach: The diameter and spacing of 100-, 150-, 200-, 300-μm pit array on the surface of 304 steel were calculated using a M-DPSS-50 semiconductor laser device. Then, the textured surface was nitriding-treated using a nitriding salt bath device. The chemical composition, surface morphology and surface microhardness of the composite-modified surface were measured by X-ray diffraction and by using an optical microscope and a microhardness tester. The tribological characteristics of the composite-modified surface were tested by MRTR microcomputer-controlled multifunctional friction and wear testing machine. Findings: The result showed that a rule pit texture surface was obtained by the texture processing. The microhardness of nitriding treatment surface reached 574.27HV0.1, which significantly higher than 222.58HV0.1 of 304 steel. The composite-modified surface has excellent anti-friction and wear resistance properties when the upper specimen was GCr15 steel and ZrO2, respectively. The composite-modified surface has excellent anti-friction and anti-wear properties after long time friction under different angles. However, the friction coefficient and wear morphology of the friction pairs are not affected by the friction angle. Research limitations/implications: Because of the chosen research approach, the research results may lack generalizability. Therefore, researchers are encouraged to test the proposed propositions further. Practical implications: The paper conducted a systematic study of the tribological characteristics of 304 steel composite modification surface and provided a good basis for the extensive application of 304 steel. Social implications: The study provides a good basis for the extensive application of 304 steel. Originality/value: This paper fulfils an identified need to study the extensive application of 304 steel.
In order to improve the tribological properties of the 7075-T6 aluminum alloy used on the rotor surface, a combined method of cryogenic treatment and laser surface texture treatment was applied. Various tests, including metallographic microscopy, scanning electron microscopy, elemental analysis, microhardness measurements, were conducted to examine the wear morphology and modification mechanism of the treated 7075-T6 aluminum alloy surface. A numerical simulation model of surface texture was established using computational fluid dynamics to analyze the lubrication characteristics of V-shaped texture. The research finding that the 7075-T6 aluminum alloy experienced grain refinement during the cryogenic treatment process, enhancing the wear resistance of the V-shaped textures. This improvement delayed the progression of fatigue wear, abrasive wear, and oxidative wear, thereby reducing friction losses. The designed V-shaped texture contributes to reducing contact area, facilitating the capture and retention of abrasives, and enhancing oil film load-bearing capacity, thereby improving tribological performance. The synergistic effect of cryogenic treatment reduced the friction coefficient by 24.8% and the wear loss by 66.4%. Thus, the combination of surface texture and cryogenic treatment significantly improved the tribological properties of the 7075-T6 aluminum alloy.
30 October 2024 in Journal of Materials Engineering and Performance