7XXX series aluminum alloys (Al 7XXX alloys) are widely used in bearing components, such as aircraft frame, spars and stringers, for their high specific strength, high specific stiffness, high toughness, excellent processing, and welding performance. Therefore, Al 7XXX alloys are the most important structural materials in aviation. In this present review, the development tendency and the main applications of Al 7XXX alloys for aircraft structures are introduced, and the existing problems are simply discussed. Also, the heat treatment processes for improving the properties are compared and analyzed. It is the most important measures that optimizing alloy composition and improving heat treatment process are to enhance the comprehensive properties of Al 7XXX alloys. Among the method, solid solution, quenching, and aging of Al 7XXX alloys are the most significant. We introduce the effects of the three methods on the properties, and forecast the development direction of the properties, compositions, and heat treatments and the solution to the corrosion prediction problem for the next generation of Al 7XXX alloys for aircraft structures. The next generation of Al 7XXX alloys should be higher strength, higher toughness, higher damage tolerance, higher hardenability, and better corrosion resistance. It is urgent requirements to develop or invent new heat treatment regime. We should construct a novel corrosion prediction model for Al 7XXX alloys via confirming the surface corrosion environments and selecting the accurate and reliable electrochemical measurements.
Atmospheric pollutants of nitrogen oxides (NOx) can be reduced by selective catalytic reduction (SCR). SCR of NOx with ammonia (NH3) at low temperatures has attracted much interest for high nitric oxide (NO) conversion, and this method is dominated by catalysts. Manganese (Mn)-containing oxide catalysts exhibit high activity and selectivity for the unique redox property of manganese oxides (MnOx). The reaction mechanisms and deactivation processes are summarized in this review. SCR of NOx with NH3 follows both the Langmuir–Hinshelwood and the Eley–Rideal mechanisms, which also contribute to the nitrous oxide formation. Fast SCR has a higher reaction rate than standard SCR. Mn-containing catalysts could also be deactivated by sulfur oxides and water vapor. The deactivation process of sulfur dioxide can be classified into two categories: deposition of (NH4)2SO4 and sulfation of active sites. The deactivation caused by water vapor can be attributed to the competitive adsorption. The adsorption of water on catalysts' surface blocked the active sites, which are provided for the adsorption of NH3 and NO. Alkali, alkaline earth and heavy metal ions existing in fine fly ash can also damage the catalysts' acid sites. A notable improvement on performance was obtained when Mn-containing catalysts were doped with a transition metal, for these enhanced its adsorption capacity and oxidation ability. Furthermore, this review gives a comprehensive discussion of the synergistic mechanism between bi-metal or multi-metal oxides. Major conclusions and several possible directions for further research are presented finally.