LEPABE - Laboratory for Process Engineering, Environment, Biotechnology and Energy, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portuga
Prof. Adelio Mendes
LEPABE - Laboratory for Process Engineering, Environment, Biotechnology and Energy, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portuga
In the recent years, hydrogen has gained a considerable interest as an energy carrier useful for various applications and, particularly, for polymer electrolyte membrane fuel cells (PEMFCs) supply. Nevertheless, PEMFCs require high purity hydrogen as a feeding fuel, which shows some limitations regarding storage and transportation. Therefore, to overcome these problems, the in situ hydrogen generation has made attractive both alcohols and hydrocarbons steam reforming reaction. Among other fuels, methanol is an interesting hydrogen source because it is liquid at ambient conditions, possesses relatively high H/C ratio, low reforming temperature (200–300°C) and it is also producible from biomass. Meanwhile, there is a comprehensive literature about inorganic membrane reactors utilization for hydrogen generation via methanol steam reforming reaction. This review illustrates the earlier state of the art from an experimental point of view about hydrogen production from methanol reforming performed in both conventional and membrane reactors. Furthermore, a short overview about methanol reforming catalysts as well as a discussion on the impact of methanol steam reforming process via inorganic membrane reactors to produce hydrogen for PEMFCs supply is given
This review describes the main features of dye-sensitized solar cells (DSCs) and highlights recent breakthroughs in this promising thin-film photovoltaic (PV) technology. After a brief presentation of the commercially available technologies, the general operation principles and the most relevant characteristics of DSCs are summarized. Recent major advances in high efficiency sensitizers, nanostructured semiconductors and robust electrolytes offer an opportunity for DSCs integration into the marketplace. With attractive features, like low-cost potential, simple processing, wide range of applicability – from low-power electronics to semi-transparent windowpanes for electricity generation – and good performance under typical operating conditions, these cells are one step from large-scale commercialization. We describe major strategies that are under way to make DSCs a key technology in the future PV paradigm.
1 September 2016 in Applied Catalysis B: Environment and Energy