Graphite Creek is an unusual flake graphite deposit located on the Seward Peninsula, Alaska, USA. We present field observations, uranium-lead (U–Pb) monazite and titanite geochronology, carbon (C) and sulfur (S) stable isotope geochemistry, and graphite Raman spectroscopy data from this deposit that support a new model of flake graphite ore genesis in high-grade metamorphic environments. The Graphite Creek deposit is within the second sillimanite metamorphic zone of the Kigluaik Mountains gneiss dome. Flake graphite, hosted in sillimanite-gneiss and quartz-biotite paragneiss, occurs as disseminations and in sets of very high grade (up to 50 wt.% graphite), semi-massive to massive graphite lenses 0.2 to 1 m wide containing quartz, sillimanite, inclusions of garnet porphyroblasts, K-feldspar, and tourmaline. Restitic garnet, sillimanite, graphite, and biotite accumulations indicate a high degree of anatexis and melt loss. Strong yttrium depletion in monazite, high europium ratios (Eu/Eu*), and excursions of high strontium and thorium concentrations are consistent with biotite dehydration melting. Monazite and titanite U–Pb ages record peak metamorphism from ~ 97 to 92 million years ago (Ma) and a retrograde event at ~ 85 Ma. Raman spectroscopy confirms the presence of carbonaceous material and highly ordered, crystalline graphite. Graphite δ¹³C_VPDB values of − 30 to − 12‰ and pyrrhotite δ³⁴S_VCDT values of − 14 to 10‰ are consistent with derivation from organic carbon and sulfur in sedimentary rocks, respectively. These data collectively suggest that formation of massive graphite lenses occurred approximately synchronously with high-temperature metamorphism and anatexis of a highly carbonaceous pelitic protolith. Melt extraction and fluid release associated with anatexis were likely crucial for concentrating graphite. High-temperature, graphitic migmatite sequences within high-strain shear zones may be favorable for the occurrence of high-grade flake graphite deposits.

Magmatism in the southern Grenville Province records a collisional and postcollisional history during the period 1.20–1.15 Ga in the Adirondack Lowlands (New York State, USA) and the Frontenac terrane (Ontario, Canada). The 1.20 Ga bimodal Antwerp-Rossie suite of the Adirondack Lowlands was produced by subduction in the Trans-Adirondack backarc basin. This was followed by intrusion of the 1.18 Ga alkalic to calc-alkalic Hermon granite, which may have been generated by melting of metasomatized mantle during collision of the Adirondack Lowlands and Frontenac terrane during the Shawinigan orogeny. The Hyde School gneiss plutons intruded the Adirondack Lowlands at 1.17 Ga, and Rockport granite intruded into the Adirondack Lowlands and Frontenac terrane, stitching the Black Lake shear zone, which marks the boundary between these terranes. Subsequent extensional collapse and lithospheric delamination caused voluminous anorthosite-mangerite-charnockite-granite plutonism. In the Frontenac terrane, this event is represented by the 1.18–1.15 Ga Frontenac suite, which is composed predominately of ferroan granitoids produced from melting of the lower crust by underplating mafic magmas. The Edwardsville, Honey Hill, and Beaver Creek plutons are newly recognized members of this suite in the Adirondack Lowlands. High oxygen isotope ratios of this suite in the central Frontenac terrane and western Adirondack Lowlands point to the presence of underthrust altered oceanic rocks in the lower crust. Oxygen isotopes of the Frontenac suite in both terranes preclude its derivation from mantle melts alone.

Oblique convergence along strike-slip faults can lead to both distributed and localized deformation. How focused transpressive deformation is both localized and maintained along sub-vertical wrench structures to create high topography and deep exhumation warrants further investigation. The high peak region of the Hayes Range, central Alaska, USA, is bound by two lithospheric scale vertical faults: the Denali fault to the south and Hines Creek fault to the north. The high topography area has peaks over 4000 m and locally has experienced more than 14 km of Neogene exhumation, yet the mountain range is located on the convex side of the Denali fault Mount Hayes restraining bend, where slip partitioning alone cannot account for this zone of extreme exhumation. Through the application of U-Pb zircon, ⁴⁰Ar/³⁹Ar (hornblende, muscovite, biotite, and K-feldspar), apatite fission-track, and (U-Th)/He geo-thermochronology, we test whether these two parallel, reactivated suture zone structures are working in tandem to vertically extrude the Between the Hines Creek and Denali faults block on the convex side of the Mount Hayes restraining bend. We document that since at least 45 Ma, the Denali fault has been bent and localized in a narrow fault zone (<160 m) with a significant dip-slip component, the Mount Hayes restraining bend has been fixed to the north side of the Denali fault, and that the Between the Hines Creek and Denali faults block has been undergoing vertical extrusion as a relatively coherent block along the displacement “free faces” of two lithospheric scale suture zone faults. A bent Denali fault by ca. 45 Ma supports the long-standing Alaska orocline hypothesis that has Alaska bent by ca. 44 Ma. Southern Alaska is currently converging at ~4 mm/yr to the north against the Denali fault and driving vertical extrusion of the Between the Hines Creek and Denali faults block and deformation north of the Hines Creek fault. We apply insights ascertained from the Between the Hines Creek and Denali faults block to another region in southern Alaska, the Fairweather Range, where extreme topography and persistent exhumation is also located between two sub-parallel faults, and propose that this region has likely undergone vertical extrusion along the free faces of those faults.

At the Cheever Mine, located in the eastern Adirondack Mountains of the Mesoproterozoic Grenville Province, iron oxide-apatite ore forms a narrow (<3 m) sheet cross-cutting metasomatically altered, magnetite-bearing, albite-rich leucogranitic host rocks of the Lyon Mountain Granite suite. Zircon from the ore and five samples of country rock were dated by Laser Ablation-Multi-Collector-Inductively Coupled Plasma-Mass Spectrometry. The ore yielded a Concordia age of 1033.6 ± 2.9 Ma while three samples of host rock yielded ages of 1036.3 ± 2.9, 1040 ± 11, and 1043.9 ± 4.1 Ma. Two additional samples of host rock yielded older ages of 1059.6 ± 3.4 and 1066.0 ± 6.3 Ma and contain zircon xenocrystic cores with ²⁰⁷Pb/²⁰⁶Pb ages up to 1242 Ma. The zircons analyzed, including those separated from the ore, have characteristics typically associated with an igneous origin including size, shape, inclusions, oscillatory zoning, typical chondrite-normalized REE patterns, U contents, and U/Th ratios. This data establishes the age of the ore and alteration and a temporal, and likely genetic, connection between the ore and members of the Lyon Mountain Granite suite. A model invoking melting of Shawinigan country rocks, magmatic differentiation, and long-lived magmatic and metasomatic input along extensional fault conduits is proposed for the ore’s genesis. At the Cheever Mine, magmatic hydrothermal fluids and/or post-intrusion alteration appears not to have had a major impact on zircon, which preserves original U-Pb systematics.