Properties of recycled aggregate concrete (RAC) are influenced by the composition and particle size distribution of recycled coarse aggregate (RCA). The study herein designed seven distinct groups of RACs with varying aggregate fractal dimensions (D) and one group of natural concrete (NAC). The impact of D on the workability, compressive strength, resistance to chloride ion penetration, and carbonation resistance of RAC was measured. It was found that an increase in the D value led to a decrease in the slump and slump flow, with the compressive strength and chloride ion penetration increasing and then decreasing, and carbonation gradually declined. The optimal fractal dimension was thereby determined to be 2.547 by a strength model accommodating two parameters of D and the curing age. Additionally, the mass percentage of each particle size for the corresponding gradation was presented. The compressive strength and chloride permeation resistance of RAC (D = 1.0) relative to RAC (D = 2.5) was increased by 16.7% and 13.3%, respectively. Furthermore, the carbonation depth of RAC (D = 2.5) was comparable to that of NAC. Additionally, the carbonation resistance of RAC was influenced by both the size distribution and the degree of natural carbonation of RCA, resulting in four distinct features relative to NAC. It is thereby feasible to enhance RAC performance through the manipulation of RCA’s fractal dimensions.

To alleviate the heavy burden on landfilling, construction and demolition wastes (C&DWs) are recycled and reused as aggregates in cementitious materials. However, the inherent characteristics of recycled fine aggregates (RFA), such as the high crushing index and high-water absorption, magnify the reusing difficulty. Nevertheless, attributing to the high porosity and high level of calcium hydroxides existing in the old mortar, RFA is featured with a high specific surface area and a high alkalinity. These features are useful to augment the total photo-degradation of SO₂ by nano-TiO₂ (NT) intermixed mortar, leading RFA to be an excellent potential carrier to load nano-TiO₂ and prepare the composite photocatalyst. Hence, this study proposed to load NT onto the surface of RFAs and river sands (RSs) (the control) by the soaking method, preparing composite photocatalysts denoted as NT@RFA and NT@RS, respectively. The prepared composite photocatalysts were then utilized as sands in photocatalytic mortar to evaluate for SO₂ degradation. Experiments identified a 50% higher amount of NT was loaded onto the surface of FRA relative to the control. This higher loading amount plus higher alkalinity ultimately translated into a higher photocatalytic activity. In addition, the mortar containing NT@RFA exhibited 46.3% higher physiochemical absorption and 23.9% higher photocatalytic activity than that containing NT@RS. In addition, the durability, embodied by the reuse and anti-abrasive properties, of NT@RFA exceeded that of NT@RS. The overall findings reveal that the NT@RFA not only garners beneficial effect from the high porosity but also generates positive effect from the high alkalinity. Though a number of studies deal with building materials with NT, this study is the first to load NT onto RFA and prepare composite photocatalysts which were then used as fine aggregates in building materials. Consequently, this study proves the potential high-added-value reusability of RFA in green construction materials and provides a low-cost, high-efficiency approach to degrade atmospheric SO₂.