The potential applications of graphene and its derivatives dispersed nanolubricants for efficient lubrication of mating components is evident from ever-increasing research trend.
Herein, an intercalation modification technique is proposed to improve the anticorrosion performance of polymeric coatings. Molybdate, an inhibitor, was intercalated to bestow inhibitive attributes, while functionalization of the layered double hydroxide (LDH) reservoir was performed to augment the interfacial adhesion of LDH with the polymer matrix and steel surfaces. The intercalation and functionalization of Mg–Al–LDH was characterized by Fourier-transform infrared spectroscopy, X-ray diffraction, and thermogravimetric analysis. The corrosion inhibition effectiveness of the prepared composite coating was analyzed using potentiodynamic polarization and electrochemical impedance spectroscopy. The electrochemical results revealed that the protective performance of epoxy coating was significantly enhanced by the addition of functionalized double hydroxide. The corrosion protection efficiency of the composite coating was improved by more than 98%, while the corrosion rate was lowered by ~98%, respectively, with the addition of 1 wt.% of functionalized LDH.
Thermally reduced graphene oxide (TRGO) was incorporated as a reinforcing filler in the epoxy resin to investigate the effect on the mechanical properties of carbon fiber (CF)/epoxy composites. At first, the epoxy matrix was modified by adding different wt % of TRGO from 0.05 to 0.4 wt % followed by the preparation of TRGO/CF/epoxy composites througha vacuum-assisted resin transfer molding process. The prepared TRGO was characterized by using Fourier transform infrared spectroscopy, Raman Spectroscopy and field emission scanning electron microscopy (FE-SEM) techniques. It was observed that the wrinkled structure of synthesized TRGO may be helpful to interlock with the epoxy resin and CF.The inter-laminar shear strength, in-plane fracture toughness and impact strength increased by ~67%, 62% and 93% at 0.2 wt % of TRGO loading in the CF/epoxy composites as compared to the CF reinforced epoxy. The mechanical properties of the hybrid composites decreased beyond the 0.2 wt % of TRGO incorporation in the epoxy resin. The fracture surfaces of the hybrid composites were studied by FE-SEM image analysis to investigate the synergistic effect of TRGO in the CF/epoxy composite. This study suggested that TRGO could be used asgood nanofiller to resist the matrix and fiber fracture.
Steady state characteristics of finite hydrostatic double layer porous oil journal bearing are investigated theoretically by incorporating tangential velocity slip at the porous-film interface given by Beavers–Joseph. The governing equations for flow in the porous medium and modified Reynolds equation in the film region are solved simultaneously using finite difference method. The effects of slip and design variables such as feeding parameter, bearing number, eccentricity ratio, slenderness ratio, and anisotropy of permeability have been investigated on bearing performance characteristics like load-carrying capacity, attitude angle, friction variable, and volume flowrate. The results are depicted in the form of graphs that can be utilized during design.
Molybdenum disulfide (MoS2) was functionalized by cetyltrimethylammonium bromide (CTAB) through a one-pot hydrothermal technique, and subsequently, linear low-density polyethylene (LLDPE) composites were prepared. The attachment of alkyl chains of CTAB onto the MoS2 surface was confirmed by Fourier transform infrared spectroscopy (FTIR). The enhanced mechanical properties of the composites relative to neat LLDPE revealed good compatibility between MoS2 and LLDPE. The improvement in thermomechanical properties further substantiated good interaction between MoS2 and LLDPE. The thermal stability of the prepared composites showed a small decrease in onset degradation temperature. Nevertheless, the char residue formation was found to be promoted in the presence of MoS2.