Prof. Dr. Manuel J. Tenorio

Department of Material Science and Metallurgy Engineering and Inorganic Chemistry, Universidad de Cadiz, Cadiz, Spain

Prof. Dr. Manuel J. Tenorio

Department of Material Science and Metallurgy Engineering and Inorganic Chemistry, Universidad de Cadiz, Cadiz, Spain

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Academic Career Length

38Years (1989-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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1 July 1997 in Journal of the American Chemical Society

Journal Article

Alternative Mechanisms of the Alkyne to Vinylidene Isomerization Promoted by Half-Sandwich Ruthenium Complexes. X-ray Crystal Structures of [Cp*RuCCHCOOMe(dippe)][BPh₄] and [Cp*RuH(C⋮CCOOMe)(dippe)][BPh₄] (dippe = 1,2-bis(diisopropylphosphino)ethane; Cp* = C₅Me₅)

1 January 1993 in J. Chem. Soc., Dalton Trans.

Journal Article

Bis[1,2-bis(dimethylphosphino)ethane]dihydrogenhydridoiron(II) tetraphenylborate as a model for the function of nitrogenases

Adrian Hills

David L. Hughes

Manuel J. Tenorio

G. Jeffery Leigh

Adrian T. Rowley

The trihydride complex [FeH₃(dmpe)₂]⁺(dmpe = Me₂PCH₂CH₂PMe₂) is best represented as [FeH(H₂)(dmpe)₂]⁺, with the H–H separation in the H₂ being ca. 0.81 Å. The H₂ can be replaced by N₂, CO, MeCN, MeNC and C₂H₄. The dinitrogen complex [FeH(N₂)(dmpe)₂]⁺ may be deprotonated to yield the solutionstable, trigonal-bipyramidal species [Fe(N₂)(dmpe)₂], which can be reprotonated by HCl to yield [FeCl₂(dmpe)₂], N₂, H₂ and NH₃. The crystal structures of [FeH(H₂)(dmpe)₂]BPh₄ and [FeH(N₂)(dmpe)₂]BPh₄ have been determined.

1 July 1991 in Journal of the American Chemical Society

Journal Article

Exchange of dinitrogen between iron and molybdenum centers and the reduction of dinitrogen bound to iron: implications for the chemistry of nitrogenases

G. J. Leigh

Manuel J. Tenorio

25 October 2001 in Chemical Communications

Journal Article

Regioselective cyclization of α,ω-alkynoic acids catalysed by TpRu complexes: synthesis of endocyclic enol lactones [Tp = hydrotris(pyrazolyl)borate]

Manuel J. Tenorio

M. Carmen Puerta

Pedro Valerga

F. Javier Moreno-Dorado

Francisco M. Guerra

Guillermo M. Massanet

The σ-enynyl complex [TpRu{C(Ph)C(Ph)CCPh}(PMeⁱPr₂)] efficiently catalyses the regioselective cyclization of α,ω-alkynoic acids to yield endocyclic enol lactones having ring size up to 12 atoms.