The wearable electronic skin with high sensitivity and self-power has shown increasing prospects for applications such as human health monitoring, robotic skin, and intelligent electronic products. In this work, we introduced and demonstrated a design of highly sensitive, self-powered, and wearable electronic skin based on a pressure-sensitive nanofiber woven fabric sensor fabricated by weaving PVDF electrospun yarns of nanofibers coated with PEDOT. Particularly, the nanofiber woven fabric sensor with multi-leveled hierarchical structure, which significantly induced the change in contact area under ultra-low load, showed combined superiority of high sensitivity (18.376 kPa⁻¹, at ~100 Pa), wide pressure range (0.002–10 kPa), fast response time (15 ms) and better durability (7500 cycles). More importantly, an open-circuit voltage signal of the PPNWF pressure sensor was obtained through applying periodic pressure of 10 kPa, and the output open-circuit voltage exhibited a distinct switching behavior to the applied pressure, indicating the wearable nanofiber woven fabric sensor could be self-powered under an applied pressure. Furthermore, we demonstrated the potential application of this wearable nanofiber woven fabric sensor in electronic skin for health monitoring, human motion detection, and muscle tremor detection.

The development of highly sensitive, stretchable, and wearable textile-based electronic skin is of great value for application in human health monitoring, robot skin, and intelligent electronic devices. Here, we construct a highly sensitive and stretchable electronic fabric with a simple and low-cost electrospinning technology that enables us to simultaneously map and quantify the mechanical stresses induced by normal pressure, lateral strain, and flexion and to detect the noncontact finger proximity. The fabric is woven from composite yarns that are formed by a core-spun yarn wound helically around the surface of the elastic thread, wherein the core-spun yarn is obtained by coating a graphene (GO)-doped polyurethane (PU) nanofiber on the surface of a Ni-coated cotton yarn. The Ni-coated cotton yarn serves as conductive electrodes, and the nanofiber coating provides a dielectric layer. The three-dimensional elastic porous nanofiber structure of the dielectric layer, the fiber aggregate structure of the conductive electrode, and the helical structure of the elastic composite yarn play key roles in allowing the sensor unit of the electronic fabric to improve sensitivity, realize multiple-force sensitivities and realize stretchable and woven wearability. The sensor unit that can induce a large contact-area accumulation of the nanofiber dielectric layers under low external force exhibits excellent sensitivity (1.59 N⁻¹, <0.3 N), a wide sensing range (0–5 N), a low detection limit (0.001 N), a short response time (<50 ms), good cycling stability and repeatability, as well as high strain sensitivity over a wide range (0–100%). In addition, we demonstrate that the electronic fabric is suitable for voice recognition, noncontact airflow monitoring, finger and wrist muscle movements, and noncontact proximity of fingers. This flexible, elastically woven textile-based sensor demonstrates potential applications in wearable electronic devices and humanoid robots due to its superior performance.