In this paper, the thermal properties of graphene oxide (GO) with vacancy defects were studied using a non-equilibrium molecular dynamics method. The results showed that the thermal conductivity of GO increases with the model length. A linear relationship of the inverse length and inverse thermal conductivity was observed. The thermal conductivity of GO decreased monotonically with an increase in the degree of oxidation. When the degree of oxidation was 10%, the thermal conductivity of GO decreased by ~90% and this was almost independent of chiral direction. The effect of vacancy defect on the thermal conductivity of GO was also considered. The size effect of thermal conductivity gradually decreases with increasing defect concentration. When the vacancy defect ratio was beyond 2%, the thermal conductivity did not show significant change with the degree of oxidation. The effect of vacancy defect on thermal conductivity is greater than that of oxide group concentration. Our results can provide effective guidance for the designed GO microstructures in thermal management and thermoelectric applications.
1 April 2021 in Construction and Building Materials
The purpose of establishing a tailings dam is to safely store tailings to protect the natural environment from damage. Accidents at tailings dams are frequent, however, with serious consequences of not only threats to life and property but also the pollution of the environment. Many tailings dam accidents are caused by seepage failure. In this paper, the object of the case study is the Lixi tailings dam. Three- and two-dimensional finite element models are established. The seepage field of the project under different working conditions is simulated and the position of the phreatic line is obtained. The safety factors under different working conditions are obtained by combining the seepage field with the stable surface. Finally, the influence of different dry and upstream slope ratio on seepage and stability of tailings dam is obtained. The results show that the longer the length of the dry beach, the lower the phreatic line and the greater the safety factor. The higher the upstream slope ratio, the lower the phreatic line and the greater the safety factor.