The high cost of mineral-based fillers and their processing difficulties have necessitated the search for alternative and cheaper filler materials, usually agro-waste materials such as coconut shells. The coconut shells were carbonized, pulverized, and sieved into four particles sizes, namely; 63 μm, 150 μm, 300 μm, and 425 μm. The carbonized coconut shell particles of each particle size were used as fillers in the preparation of polypropylene-filled composites at filler loadings of 0, 10, 20, 30, and 40 wt. %. The control was the neat polypropylene of 0% filler addition. The polypropylene/carbonized coconut shell particles composites were prepared via melt blending of polypropylene and the filler in an injection molding machine to obtain composite sheets. The influence of filler loading on the mechanical properties was evaluated. The addition of fillers was found to improve the yield strength, tensile strength, tensile modulus, flexural strength, flexural modulus, and hardness of polypropylene as these mechanical properties increased with increase in filler loading. The elongation at break and modulus of resilience of the prepared polypropylene/carbonized coconut shell particles composites were, however, observed to decline with an increase in the filler loading. Compared with the neat polypropylene, the filler showed enhanced mechanical properties in the prepared composites. SEM revealed good filler–matrix interaction because of good interfacial adhesion. The incorporation of more filler resulted in the formation of more spherulite-producing nuclei, reduction of pore sizes, and enhanced particle size distribution with improved mechanical properties. Experimental data modeling showed the addition of more than 48% carbonized coconut shell particles to polypropylene would compromise property enhancement.

The fact that the microstructure of steel depends on its composition and the heat treatment given to it has been heavily exploited in the design of steel for power plant applications. To obtain a steel that can function at the higher temperature where power plants operate without failure for extended life, heat treatment is needed to produce fine and highly stable dispersion of carbides, nitrides, and intermetallic compounds in the microstructure of the material. A significant contribution also comes from solid solution strengthening by substitutional solutes. We review here various types of phases, microstructures, functions, and interacting effects of the various alloying elements in the design of steel for modern power plant application.

Several factors contribute to the development of structure and properties of aluminiumalloy castings. This study investigated the singular effect of cooling rate on the as-cast structure andmechanical properties of an aluminum-silicon eutectic alloy, keeping other factors such as pouringtemperature, melt treatments, physical and thermal properties of the mould, and alloy compositionconstant. The rate of cooling was varied by employing different casting section sizes, based on thevariation of rate of heat extraction given by solidification time as predicted by the Chvorinov’s rule.Four test bars of section sizes 10, 20, 30, and 40 mm respectively were cast in sand mould using thesame gating system. Spectrometric analysis of the alloy formulated revealed that it could be specifiedapproximately as Al-12.8Si-1.0Cu alloy. The study showed that as section size decreased from 40mm to 10 mm; the solidification time reduced (i.e. the cooling rate increased), the microstructure gotfiner, the silicon flakes became more uniformly distributed, and the mechanical properties generallyimproved. The tensile strength, ductility, and hardness all increased in the order of decreasing sectionsize, i.e. increasing cooling rate. The mechanical properties were found to be linearly correlated withsection size or cooling rate. Whereas the elongations were lower than values for pure aluminium, thestrength and hardness were significantly higher than values for the pure metal. It is concluded thatthe cooling rate modifies the microstructure and improves the mechanical properties of as-cast Al–Sieutectic alloys

Model for predicting the concentration of phosphorus removed during leaching of iron oxide ore with oxalic acid solution has been derived. The model; P = 150.5/ua was found to predict the concentration of phosphorus removed with high degree of precision, being dependent on the values of the final leaching solution pH and weight of iron oxide ore added. It was observed that the validity of the model is rooted in equation (1), where the values of both sides of the equation were correspondingly almost equal. The positive or negative deviation of each of the model-predicted values of P (removed) from those of the experimental values were found to be less than 26%, which is quite within the range of acceptable deviation limit for experimental results. Keywords: Phosphorus, oxalic acid, iron oxide ore, leaching, modeling

Model for calculating the quantity of water that evaporated during oven drying of Otamiri clay has been derived. The model; j = exp ((In1/2.9206)18) showed that the quantity of water that evaporated during the drying process was dependent on the drying time, the evaporation surface being constant. It was found that the validity of the model is rooted in equation (1), where both sides of the equation were correspondingly almost equal. The respective deviation of the model-predicted quantity of evaporated water from the corresponding experimental value was less than 26%, which is quite within the acceptable deviation range of experimental results, hence depicting the usefulness of the model. Keywords: Model, water, evaporation, drying, clay

Several factors contribute to the development of structure and properties of aluminiumalloy castings. This study investigated the singular effect of cooling rate on the as-cast structure andmechanical properties of an aluminum-silicon eutectic alloy, keeping other factors such as pouringtemperature, melt treatments, physical and thermal properties of the mould, and alloy compositionconstant. The rate of cooling was varied by employing different casting section sizes, based on thevariation of rate of heat extraction given by solidification time as predicted by the Chvorinov’s rule.Four test bars of section sizes 10, 20, 30, and 40 mm respectively were cast in sand mould using thesame gating system. Spectrometric analysis of the alloy formulated revealed that it could be specifiedapproximately as Al-12.8Si-1.0Cu alloy. The study showed that as section size decreased from 40mm to 10 mm; the solidification time reduced (i.e. the cooling rate increased), the microstructure gotfiner, the silicon flakes became more uniformly distributed, and the mechanical properties generallyimproved. The tensile strength, ductility, and hardness all increased in the order of decreasing sectionsize, i.e. increasing cooling rate. The mechanical properties were found to be linearly correlated withsection size or cooling rate. Whereas the elongations were lower than values for pure aluminium, thestrength and hardness were significantly higher than values for the pure metal. It is concluded thatthe cooling rate modifies the microstructure and improves the mechanical properties of as-cast Al–Sieutectic alloys