Nickel-Copper (Ni-Cu) alloys exhibit simultaneously high strength and toughness, excellent corrosion resistance, and may show good wear resistance. Therefore, they are widely used in the chemical, oil, and marine industries for manufacturing of various components of equipment, such as: drill collars, pumps, valves, impellers, fixtures, pipes, and, particularly, propeller shafts of marine vessels. Processing technology includes bar forging, plate and tube rolling, wire drawing followed by heat treatment (for certain alloy compositions). Growing demand for properties improvement at a reduced cost initiate developments of new alloy chemistries and processing technologies, which require a revision of the microstructure-properties relationship. This work is dedicate to analysis of publicly available data for the microstructure, mechanical properties and strengthening mechanisms in Ni-Cu alloys. The effects of composition (Ti, Al, Mn, Cr, Mo, Co contents) and heat treatment on grain refinement, solid solution, precipitation strengthening, and work hardening are discussed.

Two Ni–Cu alloys, Monel K500 and FM60, with various contents of Ti, Mn, Al, Fe and C were deposited in the form of plates on a metal base plate using wire arc additive manufacturing technology. Three deposition speeds have been applied: 300, 400 and 500 mm/min. To modify the as-welded microstructure and properties, the deposited walls/plates have been subjected to two heat treatment procedures: annealing at 1100 °C for 15 min, slow cooling to 610 °C, ageing at this temperature for 8 h and either (i) air cooling to room temperature or (ii) slow cooling to 480 °C, ageing at this temperature for 8 h and air cooling to room temperature. The microstructure characterisation and mechanical properties testing have been conducted for each of the 18 chemistry/processing conditions. The dependences of the precipitate’s parameters (size, number density and chemistry), mechanical properties and wear resistance on the alloy composition, deposition speed and heat treatment have been obtained. In Monel K500, the precipitates were mainly of the TiC/TiCN type, and in FM60, they were of the MnS and TiAlMgO types. Monel K500 has shown higher hardness, strength, toughness and wear resistance in all studied conditions. Ageing at 610 °C improved properties in both alloys following the precipitation of new particles. Ageing at 480 °C could result in a properties loss if the particle coarsening (decrease in number density) took place.

Global economy requires steel with further increasing mechanical properties and simultaneously decreasing price. In mass manufacturing three major methods can be used to increase strength: (i) increase microalloying element additions (increases cost), (ii) decrease deformation temperature and (iii) increase cooling rate after high temperature processing (both can be challenging for equipment). Thin strip casting is an effective way to reduce cost as it brings a reduction in number of deformation passes and shortens the production line. However, the mechanical properties can be missed due to insufficient microstructure development. In this article, we investigate a recently proposed technology based on Austenite Conditioning followed by Accelerated Cooling and Warm Deformation (AC²WD). Two low carbon steels microalloyed with either 0.012Ti or 0.1Mo-0.064Nb-0.021Ti (wt.%) were subjected to three processing modifications of the AC²WD-technology with two, one or no deformation of cast microstructure in the austenite temperature field. The Ti- and MoNbTi-steels exhibited 685–765 MPa and 880–950 MPa of the yield stress, 780–840 MPa and 1035–1120 MPa of tensile strength, and 20–30% and 22–24% of elongation to failure, respectively. The nature of strengthening mechanisms associated with the AC²WD-technology is discussed on the basis of detailed microstructure characterisation.