Field application of liquid animal manure (slurry) is a significant source of ammonia (NH3) emission to the atmosphere. It is well supported by theory and previous studies that air temperature effects NH3 flux from field applied slurry. The objectives of this study was to statistically model the response of temperature at the time of application on cumulative NH3 emission. Data from 19 experiments measured with the same system of dynamic chambers and online measurements were included. A generalized additive model allowing to represent non-linear functional dependences of the emission on the temperature revealed that a positive response of the cumulative NH3 emission on the temperature at the time of application up to a temperature of approximately 14 °C. Above that, the temperature effect is insignificant. Average temperature over the measuring period was not found to carry any additional information on the cumulative NH3 emission. The lack of emission response on temperature above a certain point is assumed to be caused by drying out of the slurry and possible crust formation. This effect is hypothesized to create a physical barrier that reduce diffusion of NH3 to the soil surface, thereby lowering the emission rate. Furthermore, the effect of the interaction between soil type and application technique and the effect of dry matter content of the slurry was derived from the model, and found to be significant on cumulative NH3 emission predictions.
23 February 2022 in Journal of Environmental Management
Land spreading of liquid animal manure (slurry) is a major source of atmospheric emissions. Ammonia (NH3) emission is of concern, as it is one of the main contributors to ambient air pollution and nitrogen deposition. Storage and field acidification of the slurry prior to application is used to mitigate NH3 emission, but the effect of acidification on emissions of odorous non-methane volatile organic compounds (NMVOC) has not been investigated, and there is a scarcity of data investigating the effect of field acidification. Four field experiments, two with cattle slurry and two with pig slurry, were performed. Ammonia and NMVOC emissions were measured simultaneously in a system of dynamic chambers and online measurements by cavity ring-down spectroscopy (CRDS) and proton-transfer-reaction mass spectrometry (PTR-MS). The system allowed for a high time resolution and low variation. All four experiments were performed under cold conditions (<10°C average temperature). Storage and field acidification significantly lowered the NH3 emission by 79 ± 18% and 30 ± 6% on average, respectively. The NMVOC cumulative emission increased by 202 ± 133% and 17 ± 16% on average after storage and field acidification, respectively, even if the increase was only significant for storage acidification. Storage acidification significantly increased the emissions of odour at most measuring times. The increases of cumulative NMVOC emissions and odour was primarily caused by higher emissions of volatile fatty acids.
12 August 2023 in Agriculture, Ecosystems & Environment
Soil surface measurements play an important role in the performance assessment of tillage operations and are relevant in both academic and industrial settings. Manual soil surface measurements are time-consuming and laborious, which often limits the amount of data collected. An experiment was conducted to compare two approaches for measuring and analysing the cross-sectional area and geometry of a furrow after a trailing shoe sweep. The compared approaches in this study were a manual pinboard and a Light Detection and Ranging (LiDAR) sensor. The experiments were conducted in coarse sand and loamy sand soil bins exposed to three levels of irrigation. Using the LiDAR, a system for generating 3D scans of the soil surface was obtained and a mean furrow geometry was introduced to study the geometrical variations along the furrows. A comparison of the cross-sectional area measurements by the pinboard and the LiDAR showed up to 41% difference between the two methods. The relation between irrigation and the resulting furrow area of a trailing shoe sweep was investigated using the LiDAR measurements. The furrow cross-sectional area increased by 11% and 34% under 20 mm and 40 mm irrigation compared to non-irrigated in the coarse sand experiment. In the loamy sand, the cross-sectional area increased by 17% and 15% by irrigation of 20 mm and 40 mm compared to non-irrigated measured using the LiDAR.
2 April 2023 in Journal of Environmental Management