Excessive intake of fluoride can cause adverse health effects. Consumption of tea as a popular drink could be a potential source of fluoride exposure to humans. This research aimed to evaluate the fluoride concentration in tea among the Iranian people using the available data in the literature and to assess the health risk related to the consumption of tea in men, women, and children. The health risk assessment was conducted using the chronic daily intake and hazard quotient according to the approach suggested by the Environmental Protection Agency. The fluoride content in published studies varied noticeably, ranging from 0.13 to 3.27 mg/L. The results revealed that the hazard quotient (HQ) in age groups of women (21–72 years) and children (0–11 years) was within the safe zone (HQ < 1) which showed that there was no potential of non-carcinogenic risk associated with drinking tea in these groups. However, in one case of the men (21–72 years), the HQ > 1 which shows a probable risk of fluorosis. The order of non-carcinogenic health risks in the studied groups was in the order of men > women > children. The results of this can be useful for organizations with the responsibility of human health promotion.

Metal-organic frameworks (MOFs) are currently recognized as unique platforms for environmental studies. This study evaluated the potential of nine MOFs from ZIF-8, ZIF-67, and UIO-66 families for the removal of ciprofloxacin (CIP), a toxic, bio-accumulative, and persistent fluoroquinolone antibiotic. ZIF-67-SO₄, with a rhombic crystalline morphology and 1375 m²/g BET surface area, has the highest CIP adsorption efficiency among the studied MOFs. The mathematical sorption model predicted that the highest CIP removal (99.2%) occurs when adsorbent dose, pH, and agitation time are adjusted to 6.82, 832.4 mg/L, and 39.95 min, respectively. Further studies revealed that the CIP adsorbed onto ZIF-67-SO₄ in monolayer (q_max: 2537.5 mg/g) and chemisorption controlled the rate of the process. Mass transfer kinetic coefficients improved significantly by sonication at 35 KHz in comparison with mechanical agitation. Thermodynamic parameters (minus signs of ∆G° [7.8 to 14.2], positive signs of ∆H° (58.9 KJ/mol), and ∆S° (0.23 KJ/mol·K)) demonstrated the spontaneous, endothermic, and chemical sorption of CIP. The level of cobalt leached from ZIF-67-SO₄ structure varied 1.2–4.5 mg/L, depending on pH, mixing time, and agitation type. In conclusion, the excellent adsorption properties of ZIF-67-SO₄ for CIP, made it an outstanding candidate for environmental protection purposes.

• Onions have medicational features such as anti-cancer, antimicrobial, antiviral, and antifungal. • Onions are rich in edible flavonoids. • Due to their physiology and ecosystem, onions have the property of accumulating heavy metals. • Onion consumption per capita in Iran is higher than in neighboring countries.

The aim of this study was to Monitoring of physical and chemical characteristics of ground water including Ca2+, Mg2+, EC, pH, TDS, TH, HCO3- , Na+, K+, Cl-, SAR, %Na and SO42- in Zanjan city, Iran. For assessing the physic-chemical parameters from 15 wells, water samples 4 times at different times were collected and examined. Data were analyzed using R and Arc GIS software. According to the calculated correlation coefficients, the highest correlation Coefficient belonged to TDS-EC while HCO3- and Cl- showed low and weak correlations. However, Na+, Mg2+, K+, Ca2+ exhibited good positive correlations with EC and TDS. The results show that the water in the study area at the time of the study was based on the WHO standards and appropriate for drinking.