Natural occurrence and anthropogenic practices contribute to the release of pollutants, specifically heavy metals, in water over the years. Therefore, this leads to a demand of proper water treatment to minimize the harmful effects of the toxic heavy metals in water, so that a supply of clean water can be distributed into the environment or household. This review highlights several water treatment methods that can be used in removing heavy metal from water. Among various treatment methods, the adsorption process is considered as one of the highly effective treatments of heavy metals and the functionalization of adsorbents can fully enhance the adsorption process. Therefore, four classes of adsorbent sources are highlighted: polymeric, natural mineral, industrial by-product, and carbon nanomaterial adsorbent. The major purpose of this review is to gather up-to-date information on research and development on various adsorbents in the treatment of heavy metal from water by emphasizing the adsorption capability, effect of pH, isotherm and kinetic model, removal efficiency and the contact of time of every adsorbent.

A desired copolymer, cellulose-graft-polyacrylonitrile was synthesized by a free radical initiating process and optimum reaction conditions were determined for maximum grafting yield (125%). The nitrile functionalities of the grafted copolymers were converted into the amidoxime ligand by oximation reaction. The kenaf cellulose, cellulose grafted copolymer and poly(amidoxime) ligand were characterized by infrared spectroscopy, field emission scanning electron microscopy, transmission electron microscopy and X-ray photoelectron spectroscopy. The pH of the solution acts as a key factor to achieve the optical detection of metal ions using complexation of this ligand with some transition metal ions. The reflectance spectra of the [M–ligand]ⁿ⁺ complex was found to have a highest absorbance ranging from 97 to 99.9% at pH 6. The reflectance spectra were increased by increasing Cu²⁺ ion concentration and a broad peak at 700 nm was observed which indicates the charge transfer (π–π transition) complex. The adsorption capacity with copper was found to be superior; 326.6 mg g⁻¹. The adsorption capacities for other transition metal ions were also found to be strong; Fe³⁺, Co³⁺, Mn²⁺, Cr³⁺, Ni²⁺ and Zn²⁺ were 273.6, 271.6, 241.7, 228.2, 204.2 and 224.3 mg g⁻¹, respectively at pH 6. The experimental data of all metal ions fitted significantly with the pseudo-second-order rate equation. The data proved that the transition metal ion sorption onto ligands was well fitted with the Langmuir isotherm model (R² > 0.99), which suggest that the cellulose-based adsorbent known as poly(amidoxime) ligand surface is homogenous and monolayer. The reusability was checked by the sorption/desorption process for seven cycles and the sorption and extraction efficiency in each cycle was determined. The new type of adsorbent can be reused in many cycles without any significant loss in its original sensing and removal performances.

Three novel bent-shaped monomers, namely 1,3-phenylene bis-{4-[4-(n-allyloxyalkyloxy)phenylazo]benzoate} 5a–c, containing azobenzene as side arms, resorcinol as central units and terminal double bonds as polymerisable functional groups were synthesised and characterised. The mesophase behaviour was investigated by polarising optical microscopy, differential scanning calorimetry and X-ray diffraction measurements and it was found that all three compounds display SmA_intercal mesophases. These bent-shaped molecules exhibit strong photoisomerisation behaviour in solutions in which trans to cis isomerisation takes about 50 seconds whereas the reverse process takes almost 31 hours.