The alteration of platinum group minerals (PGM) of eluval, proximal, and distal placers associated with the Ural-Alaskan type clinopyroxenite-dunite massifs were studied. The Isovsko-Turinskaya placer system is unique regarding its size, and was chosen as research object as it is PGM-bearing for more than 70 km from its lode source, the Ural-Alaskan type Svetloborsky massif, Middle Urals. Lode chromite-platinum ore zones located in the Southern part of the dunite “core” of the Svetloborsky massif are considered as the PGM lode source. For the studies, PGM concentrates were prepared from the heavy concentrates which were sampled at different distances from the lode source. Eluvial placers are situated directly above the ore zones, and the PGM transport distance does not exceed 10 m. Travyanistyi proximal placer is considered as an example of alluvial ravine placer with the PGM transport distance from 0.5 to 2.5 km. The Glubokinskoe distal placer located in the vicinity of the Is settlement are chosen as the object with the longest PGM transport distance (30–35 km from the lode source). Pt-Fe alloys, and in particular, isoferroplatinum prevail in the lode ores and placers with different PGM transport distance. In some cases, isoferroplatinum is substituted by tetraferroplatinum and tulameenite in the grain marginal parts. Os-Ir-(Ru) alloys, erlichmanite, laurite, kashinite, bowieite, and Ir-Rh thiospinels are found as inclusions in Pt-Fe minerals. As a result of the study, it was found that the greatest contribution to the formation of the placer objects is made by the erosion of chromite-platinum mineralized zones in dunites. At a distance of more than 10 km, the degree of PGM mechanical attrition becomes significant, and the morphological features, characteristic of lode platinum, are practically not preserved. One of the signs of the significant PGM transport distance in the placers is the absence of rims composed of the tetraferroplatinum group minerals around primary Pt-Fez alloys. The sie of the nuggets decreases with the increasing transport distance. The composition of isoferroplatinum from the placers and lode chromite-platinum ore zones are geochemically similar.
This paper provides a detailed geological description of the Serebryansky Kamen gabbro massif and copper–precious metal mineralization found for the first time within it. The first data on the distribution and localization of disseminated copper–precious metal mineralization in the central part of the massif have been obtained. It was found that copper sulfides (bornite, chalcopyrite, digenite, and chalcocite) are predominantly hosted in melanocratic taxitic varieties of amphibole gabbro. Elevated precious-metal concentrations were measured and precious-metal minerals were identified for the first time in gabbro enriched in sulfides in the northern part of the Ural platinum belt. The Pd–Pt–Fe–Cu intermetallic compounds, sulfide (vysotskite), tellurides (merenskyite, Pd-melonite, kotulskite), bismuthotellurides (michenerite), arsenides, platinum and palladium arsenotellurides (sperrylite, arsenopalladinite), and native gold were identified. Based on a geochemical survey, the resources of copper and precious metals in the Serebryansky Kamen gabbro massif are 760.1 kt of Cu and 97.1 t of precious metals, dominated by Au and Pd. The identified mineralized zones are comparable to the complex Volkovsky deposit in size, structure, and composition. A geological and genetic model is proposed, which can be widely used in prospecting for copper and precious metals in the gabbroic parts of dunite–clinopyroxenite–gabbro massifs.
The new data for the geology and mineralogy of the platinum group element (PGE) mineralization related to the chromite–platinum ore zones within the dunite of the Svetly Bor and Veresovy Bor massifs in the Middle Urals are discussed. The geological setting of the chromite–platinum ore zones, their platinum content, compositional and morphological features of the platinum group minerals (PGM) are compared to those within the Nizhny Tagil massif, the world standard of the zonal complexes in the Platinum Ural belt. The chromite–platinum orebodies are spatially related to the contacts between differently granular dunites. Majority of PGM are formed by Pt–Fe alloys that are close in terms of stoichiometry to isoferroplatinum (Pt3Fe), and associated with Os–Ir alloys, Ru–Os and Ir–Rh sulfides, and Ir–Rh thiospinels of the cuproiridsite–cuprorhodsite–ferrorhodsite solid solution. The tetraferroplatinum (PtFe)–tulameenite (PtFe0.5Cu0.5) solid solution and Pt–Cu alloys belong to the later PGM assemblage. The established features of the chromite–platinum ore zones testify to the highly probable identification of the PGE mineralization within the dunite of the Svetly Bor and Vesesovy Bor massifs and could be used in prospecting and exploration for platinum.
The Eastern Kazakhstan Gold Belt is a major black-shale-hosted gold province in Central Asia where the main types of deposits comprise mineralized zones with auriferous sulfides (micro- and nano-inclusions of gold and refractory gold) and quartz veins with visible gold. The quartz vein deposits are economically less important but may potentially represent the upper parts of bigger ore systems concealed at depth. In this work, the mineralogy of the quartz vein deposits and related wall rock alteration zones was studied using microscopy and SEM-EDS analysis, and the geochemical dispersion of the ore elements in primary alteration haloes was documented utilizing spatial distribution maps and statistical treatment methods. The studied auriferous quartz veins are classified as epizonal black-shale-hosted orogenic gold deposits. The veins generally have linear shapes with an average width of ca. 1 m and length up to 150 m and contain high-grade native gold with minor amounts of sulfides. In supergene oxidation zones, the native gold is closely associated with Fe-hydroxide minerals cementing brecciated zones within the veins. The auriferous quartz veins are usually enclosed by the wall rock alteration envelopes, where two types of alteration are distinguished. Proximal phyllic alteration (sericite-albite-pyrite ± chlorite, Fe-Mg-Ca carbonates, arsenopyrite, and pyrrhotite) develops as localized alteration envelopes, and pervasive carbonation accompanied by chlorite ± sericite and albite is the dominant process in the distal alteration zones. The rocks within the alteration zones are enriched in Au and chalcophile elements, and three groups of chemical elements showing significant positive mutual correlation have been identified: (1) an early geochemical assemblage includes V, P, and Co (±Ni), which are the chemical elements characteristic for black shale formations, (2) association of Au, As, and other chalcophile elements is distinctly overprinting, and manifests the main stage of sulfide-hosted Au mineralization, and (3) association of Bi and Hg (±Sb and U) includes the chemical elements that are mobile at low temperatures, and can be explained by activity of the late-stage hydrothermal or supergene fluids. The chalcophile elements show negative slopes from proximal to distal alteration zones and form overlapping positive anomalies on spatial distribution mono-elemental maps. Thus, the geochemical methods can provide useful tools to delineate the ore elemental associations and to outline reproducible anomalies for subsequent regional gold prospecting.
1 November 2018 in Moscow University Geology Bulletin
The mineralogical and geochemical patterns of platinum-bearing vein–impregnated and massive chromitite from dunite of the Svetloborsky, Veresovoborsky, and Kamenushensky clinopyroxenite–dunite...