High-entropy oxides (HEOs) have attracted more and more attention because of their unique structures and potential applications. In this work, (FeCoCrMnZn)₃O₄ HEO powders were synthesized via a facile solid-state reaction route. The confirmation of phase composition, the observation of microstructure, and the analysis of crystal structure, distribution of elements, and valences of elements were conducted by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS), respectively. Furthermore, a (FeCoCrMnZn)₃O₄/nickel foam ((FeCoCrMnZn)₃O₄/NF) electrode was prepared via a coating method, followed by the investigation of its supercapacitor performance. The results show that, after calcining (FeCoCrMnZn)₃O₄ powders at 900 °C for 2 h, a single spinel structure (FCC, Fd-3m, a = 0.8399 nm) was obtained with uniform distribution of Fe, Co, Cr, Mn, and Zn elements, the typical characteristic of a high-entropy oxide. In addition, the mass specific capacitance of the (FeCoCrMnZn)₃O₄/NF composite electrode was 340.3 F·g⁻¹ (with 1 M KOH as the electrolyte and 1 A·g⁻¹ current density), which indicates that the (FeCoCrMnZn)₃O₄ HEO can be regarded as a prospective candidate for an electrode material in the field of supercapacitor applications.

Recently, metal phosphides have attracted considerable attention as promising electrode materials for supercapacitors. In this work, FeP nanotube arrays have been successfully synthesized on carbon cloth using ZnO nanorod arrays as the sacrificial templets, via a phosphidation process. The dimensions of the FeP nanotubes are characterized using SEM and TEM showing the diameter to be approximately 200 nm and with a wall thickness of 50–100 nm. The tubular structure of FeP nanotubes provides a facile ion pathway and reduced inner inactive material, thus they are favorable for supercapacitor applications. As a result, the as-synthesized FeP nanotube arrays deliver an improved specific capacitance of 149.11 F g ⁻¹ and a high areal capacitance of 300.1 mF cm ⁻² at a current density of 1 mA cm ⁻² . Furthermore, an MnO ₂ //FeP solid-state asymmetric supercapacitor was fabricated with a high areal capacitance of 142 mF cm ⁻² , which indicates the great potential of FeP nanotube arrays to be a high-performing negative electrode material for supercapacitors.