Switchgrass is a high yielding, low-input intensive, native perennial grass that has been promoted as a major second-generation bioenergy crop. Raw switchgrass is not a readily acceptable feedstock in existing power plants that were built to accommodate coal and peat. The objective of this research was to elucidate some of the characteristics of switchgrass biochar produced via carbonization and to explore its potential use as a solid fuel. Samples were carbonized in a batch reactor under reactor temperatures of 300, 350 and 400 °C for 1, 2 and 3 h residence times. Biochar mass yield and volatile solids decreased from 82.6% to 35.2% and from 72.1% to 43.9%, respectively, by increasing carbonization temperatures from 300 °C to 400 °C and residence times from 1 h to 3 h. Conversely, biochar heating value (HV) and fixed carbon content increased from 17.6 MJ kg⁻¹ to 21.9 MJ kg⁻¹ and from 22.5% to 44.9%, respectively, under the same conditions. A biomass discoloration index (BDI) was created to quantify changes in biochar colors as affected by the two tested parameters. The maximum BDI of 77% was achieved at a carbonization temperature of 400 °C and a residence time of 3 h. The use of this index could be expanded to quantify biochar characteristics as affected by thermochemical treatments. Carbonized biochar could be considered a high quality solid fuel based on its energy content.

The objectives of this article are to offer a comprehensive evaluation of the opportunities and barriers for swine manure conversion technologies and to shed light on the gaps that might require further investigation to improve the applicability of these technologies. The challenges of manure management have been propagated alongside the global growth of swine production. Various technologies that target the production of energy, fuels, and bioproducts from swine manure have been reported. These technologies include pretreatments, i.e., drying, and solid separation; biological techniques, i.e., composting, anaerobic digestion, and biodrying; and thermochemical techniques, i.e., combustion, gasification, pyrolysis, liquefaction, and carbonization. The review highlights the yields and qualities of products, i.e., energy, gaseous fuel, liquid fuel, and solid fuel, of each technology. It exhibits that the choice of a conversion technology predominantly depends on the feedstock properties, the specifics of the conversion technique, the market values of the end products as well as the local regulations. The challenges associated with the presented techniques are discussed to ameliorate research and development in these areas. The notable finding of this paper is that there is a need for full-scale research in the area of thermochemical conversion of solid-separated swine manure.

Sustainable swine manure management is critical to reducing adverse environmental impacts on surrounding ecosystems, particularly in regions of intensive production. Conventional swine manure management practices contribute to agricultural greenhouse gas (GHG) emissions and aquatic eutrophication. There is a lack of full-scale research of the thermochemical conversion of solid-separated swine manure. This study utilizes a consequential life cycle assessment (CLCA) to investigate the environmental impacts of the thermal gasification of swine manure solids as a manure management strategy. CLCA is a modeling tool for a comprehensive estimation of the environmental impacts attributable to a production system. The present study evaluates merely the gasification scenario as it includes manure drying, syngas production, and biochar field application. The assessment revealed that liquid storage of manure had the highest contribution of 57.5% to GHG emissions for the entire proposed manure management scenario. Solid-liquid separation decreased GHG emissions from the manure liquid fraction. Swine manure solids separation, drying, and gasification resulted in a net energy expenditure of 12.3 MJ for each functional unit (treatment of 1 metric ton of manure slurry). Land application of manure slurry mixed with biochar residue could potentially be credited with 5.9 kg CO₂-eq in avoided GHG emissions, and 135 MJ of avoided fossil fuel energy. Manure drying had the highest share of fossil fuel energy use. Increasing thermochemical conversion efficiency was shown to decrease overall energy use significantly. Improvements in drying technology efficiency, or the use of solar or waste-heat streams as energy sources, can significantly improve the potential environmental impacts of manure solids gasification.