Flexible picene thin film field-effect transistors (FETs) have been fabricated with parylene gate dielectric on polyethylene terephthalate substrates. The picene thin film FETs show p-channel output/transfer characteristics and the field-effect mobility reaches in vacuum. The FET shows a clear gas sensing effect and negligible hysteresis in the transfer curves, indicating a possible application of the transistor as selective gas sensor. Furthermore, it has been found that the parylene gate dielectric can eliminate a reduction in on-state drain current caused by continuous bias-voltage application which is observed if a gate dielectric is used.
A new cobalt(II) complex bearing a pair of cobalt(III) tris-chelate complexes as metalloligands was prepared. The CoII ion possesses an ideal trigonal antiprismatic geometry because of the intermolecular hydrogen-bonds between the metalloligands via counter anions. This complex exhibits slow magnetic relaxation under a dc field reminiscent of a single-molecule magnet behavior.