Polypropylene/Maleic anhydride compatibilized polypropylene (MPP)/Organo-Vermiculite nanocomposites with different clay loadings were prepared via melt mixing using a twin screw extruder. The vermiculite (VMT) was pre-modified with Maleic anhydride (MA) by ball milling. The mechanism of VMT modification by MA was discussed. The resultant PP/MPP/OVMT nanocomposites possess an intercalated or exfoliated structure as confirmed by both wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM). The mechanical property tests show that the tensile strength, flexural strength of these nanocomposites increase dramatically with the OVMT loading; the fracture toughness remain almost unchanged, and the Charpy impact strength decrease slightly.
This paper reports the results of a full-scale field test that was conducted to assess the performance of the use of wet-milling cement and chemical compound grouting in the same hole to reinforce a flexural fracture zone. Wet-milling cement and chemical compound grouting methods were used to treat a layer of the flexural fracture zone with a thickness of 19 m. The procedures of the cement–chemical compound grouting method were described in detail, and the results of the normal water pressure test, fatigue water pressure test, failure water pressure test, and shear wave velocity test suggested that the working effects in the epoxy testing area were better than those in the acrylic acid salt test area, which further indicated that the cement–chemical compound grouting method was feasible. In addition, the improvement mechanism of the cement–chemical compound grouting technology was studied; this method is beneficial for solving the problem of the reinforcement effect not being ideal in practical engineering and further improving the compactness of dam structures.
This study evaluates the performance degradation of spray rigid polyurethane foam (RPUF) insulation on reservoir dam structures under multi-physics coupling conditions. Focusing on characteristic environmental exposures in Hot Summer and Cold Winter (HSCW) climate zones, accelerated aging tests simulating coupled temperature–humidity effects were conducted to comparatively analyze the thermal resistance and durability evolution between unprotected and encapsulated RPUF configurations. Scanning electron microscopy (SEM), infrared spectroscopy (IR), and other methods were used to characterize and analyze the structure of RPUF. Research has shown that in HSCW climate zones, the thermal conductivity of RPUF gradually increases with the number of degradation cycles, and the insulation performance decreases, mainly due to the damage of the pore structure caused by temperature aging and the combined effect of moisture absorption aging. In comparison, the RPUF after protection can effectively slow down the rate and degree of decline of its insulation performance. On this basis, a time-varying prediction model for the thermal conductivity of RPUF under long-term service in HSCW climate environments was fitted, providing a scientific basis for the durability evaluation of reservoir dam insulation.
2 April 2022 in Journal of Wuhan University of Technology-Mater. Sci. Ed.
Hydraulic concrete suffers severe damage from high-velocity sand-bearing water flow. Traditional single-layer coating materials struggle to simultaneously satisfy the requirements of strong adhesion, high abrasion resistance, and long-term durability. In this study, a functionally graded multilayer composite coating system, designated HIR (Hybrid Epoxy–Interfacial Primer–Rubber), was developed. The HIR system comprises a hybrid acrylic–epoxy resin (HEP) top layer, a modified epoxy-based interfacial primer (EIP), and a sprayed liquid rubber (SLR) middle layer, realizing synergistic enhancement of interfacial bonding, deformation adaptability, and abrasion resistance. The results showed that the HIR achieved an adhesion strength exceeding 2.0 MPa to concrete. The HEP exhibited an elongation at break exceeding 30%, while the SLR showed an elongation at break higher than 1000%. The anti-abrasion strength of the HIR-coated concrete reached 254.35 h/(kg/m2), which is 15 times that of uncoated concrete. Moreover, the coated concrete maintained a relative dynamic elastic modulus above 95% after 300 freeze–thaw cycles. DMA revealed multiple glass transition temperatures in both SLR (24 °C, 101 °C, 137 °C) and HEP (62 °C), enabling effective energy dissipation over a wide temperature range. Through interlayer property matching and synergistic enhancement, the HIR significantly enhances both abrasion resistance and freeze–thaw durability of hydraulic concrete.