This paper delves into the pivotal role of water electrolysis (WE) in green hydrogen production, a process utilizing renewable energy sources through electrolysis. The term “green hydrogen” signifies its distinction from conventional “grey” or “brown” hydrogen produced from fossil fuels, emphasizing the importance of decarbonization in the hydrogen value chain. WE becomes a linchpin, balancing surplus green energy, stabilizing the grid, and addressing challenges in hard-to-abate sectors like long-haul transport and heavy industries. This paper navigates through electrolysis variants, technological challenges, and the crucial association between electrolytic hydrogen production and renewable energy sources (RESs). Energy consumption aspects are scrutinized, highlighting the need for optimization strategies to enhance efficiency. This paper systematically addresses electrolysis fundamentals, technologies, scaling issues, and the nexus with energy sources. It emphasizes the transformative potential of electrolytic hydrogen in the broader energy landscape, underscoring its role in shaping a sustainable future. Through a systematic analysis, this study bridges the gap between detailed technological insights and the larger energy system context, offering a holistic perspective. This paper concludes by summarizing key findings, showcasing the prospects, challenges, and opportunities associated with hydrogen production via water electrolysis for the energy transition.

The ability to accurately forecast power generation from renewable sources is nowadays recognised as a fundamental skill to improve the operation of power systems. Despite the general interest of the power community in this topic, it is not always simple to compare different forecasting methodologies, and infer the impact of single components in providing accurate predictions. In this paper we extensively compare simple forecasting methodologies with more sophisticated ones over 32 photovoltaic plants of different size and technology over a whole year. Also, we try to evaluate the impact of weather forecasts on the prediction of PV power generation.